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The Bayer process is the principal industrial means of refining bauxite to produce alumina (aluminium oxide) and was developed by Carl Josef Bayer.Bauxite, the most important ore of aluminium, contains only 30–60% aluminium oxide (Al 2 O 3), the rest being a mixture of silica, various iron oxides, and titanium dioxide. [1]
Bauxite is the main source of the rare metal gallium. [17] During the processing of bauxite to alumina in the Bayer process, gallium accumulates in the sodium hydroxide liquor. From this it can be extracted by a variety of methods. The most recent is the use of ion-exchange resin. [18]
An electrolytic cell is made of a steel shell with a series of insulating linings of refractory materials. The cell consists of a brick-lined outer steel shell as a container and support. Inside the shell, cathode blocks are cemented together by ramming paste. The top lining is in contact with the molten metal and acts as the cathode.
The liquid aluminium is removed from the cell via a siphon every 1 to 3 days in order to avoid having to use extremely high temperature valves and pumps. Alumina is added to the cells as the aluminum is removed. Collected aluminium from different cells in a factory is finally melted together to ensure uniform product and made into metal sheets.
The aluminium hydroxide is calcined to produce alumina. The process was used in France at Salindres until 1923 and in Germany and Great Britain until the outbreak of the Second World War. [4] While it has largely been replaced by the Bayer process, an updated version is still in use for processing high-silica bauxite. [5]: 90, 92–93
Bauxite was discovered in 1821 by Pierre Berthier who named it after a village named Les Beaux where he found it. [6] To obtain the alumina from the bauxite ore, a process was developed that used acid to dissolve aluminium but resulted in a product that contained large amounts of iron and titanium dissolved within which were difficult to remove. [6]
The density of aluminium is 2.70 g/cm 3, about 1/3 that of steel, much lower than other commonly encountered metals, making aluminium parts easily identifiable through their lightness. [28] Aluminium's low density compared to most other metals arises from the fact that its nuclei are much lighter, while difference in the unit cell size does not ...
Some non-ferrous materials are also used in the iron and steel industries. For example, bauxite is used as flux for blast furnaces, while others such as wolframite, pyrolusite, and chromite are used in making ferrous alloys. [3] Important non-ferrous metals include aluminium, copper, lead, tin, titanium, and zinc, and alloys such as brass.