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For a non-holonomic process function, no such function may be defined. In other words, for a holonomic process function, λ may be defined such that dY = λδX is an exact differential. For example, thermodynamic work is a holonomic process function since the integrating factor λ = 1 / p (where p is pressure) will yield exact ...
A Carnot cycle is an ideal thermodynamic cycle proposed by French physicist Sadi Carnot in 1824 and expanded upon by others in the 1830s and 1840s. By Carnot's theorem, it provides an upper limit on the efficiency of any classical thermodynamic engine during the conversion of heat into work, or conversely, the efficiency of a refrigeration system in creating a temperature difference through ...
Fick's first law relates the diffusive flux to the gradient of the concentration. It postulates that the flux goes from regions of high concentration to regions of low concentration, with a magnitude that is proportional to the concentration gradient (spatial derivative), or in simplistic terms the concept that a solute will move from a region of high concentration to a region of low ...
The inelastic mean free path (IMFP) is an index of how far an electron on average travels through a solid before losing energy.. Universal curve for the electron inelastic mean free path in elements based on equation (5) in. [1]
The contact process is a method of producing sulfuric acid in the high concentrations needed for industrial processes. Platinum was originally used as the catalyst for this reaction; however, because it is susceptible to reacting with arsenic impurities in the sulfur feedstock, vanadium(V) oxide (V 2 O 5) has since been preferred.
The Heaviside step function, or the unit step function, usually denoted by H or θ (but sometimes u, 1 or 𝟙), is a step function named after Oliver Heaviside, the value of which is zero for negative arguments and one for positive arguments. Different conventions concerning the value H(0) are in use.
Isobaric expansion of 2 cubic meters of air at 300 Kelvin to 4 cubic meters, causing the temperature to increase to 600 Kelvin while the pressure remains the same. In the first process example, a cylindrical chamber 1 m 2 in area encloses 81.2438 mol of an ideal diatomic gas of molecular mass 29 g mol −1 at 300 K. The surrounding gas is at 1 ...
As an example, consider the gas-phase reaction NO 2 + CO → NO + CO 2.If this reaction occurred in a single step, its reaction rate (r) would be proportional to the rate of collisions between NO 2 and CO molecules: r = k[NO 2][CO], where k is the reaction rate constant, and square brackets indicate a molar concentration.