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The bond valence method or mean method (or bond valence sum) (not to be mistaken for the valence bond theory in quantum chemistry) is a popular method in coordination chemistry to estimate the oxidation states of atoms. It is derived from the bond valence model, which is a simple yet robust model for validating chemical structures with ...
It was originally only used to describe the perovskite ABO 3 structure, but now tolerance factors are also used for ilmenite. [2] Alternatively the tolerance factor can be used to calculate the compatibility of an ion with a crystal structure. [3] The first description of the tolerance factor for perovskite was made by Victor Moritz Goldschmidt ...
For example, if a shaft with a nominal diameter of 10 mm is to have a sliding fit within a hole, the shaft might be specified with a tolerance range from 9.964 to 10 mm (i.e., a zero fundamental deviation, but a lower deviation of 0.036 mm) and the hole might be specified with a tolerance range from 10.04 mm to 10.076 mm (0.04 mm fundamental ...
Tolerance stackups or tolerance stacks are used to describe the problem-solving process in mechanical engineering of calculating the effects of the accumulated variation that is allowed by specified dimensions and tolerances. Typically these dimensions and tolerances are specified on an engineering drawing.
Engineering fits are generally used as part of geometric dimensioning and tolerancing when a part or assembly is designed. In engineering terms, the "fit" is the clearance between two mating parts, and the size of this clearance determines whether the parts can, at one end of the spectrum, move or rotate independently from each other or, at the other end, are temporarily or permanently joined.
Standard tolerance grades are a group of tolerances for linear sizes characterized by a common identifier. For SI measurements, a system of tolerance grades defined in ISO 286 is frequently used and identified by the letters IT followed by a number specifying how precise the requirements are, relative to the nominal size of a part.
In coordination chemistry and crystallography, the geometry index or structural parameter (τ) is a number ranging from 0 to 1 that indicates what the geometry of the coordination center is. The first such parameter for 5-coordinate compounds was developed in 1984. [ 1 ]
In physical chemistry and chemical engineering, extent of reaction is a quantity that measures the extent to which the reaction has proceeded. Often, it refers specifically to the value of the extent of reaction when equilibrium has been reached.