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1-nitropropane is produced industrially by the reaction of propane and nitric acid. This reaction forms four nitroalkanes: nitromethane, nitroethane, 1-nitropropane, and 2-nitropropane. 1-nitropropane is also a byproduct of the process for making 2-nitropropane, which is done by vapour phase nitration of propane.
The pK a values of nitromethane and 2-nitropropane are respectively 17.2 and 16.9 in dimethyl sulfoxide (DMSO) solution, suggesting an aqueous pK a of around 11. [22] In other words, these carbon acids can be deprotonated in aqueous solution. The conjugate base is called a nitronate, and behaves similar to an enolate
Nitroethane is produced industrially by treating propane with nitric acid at 350–450 °C. This exothermic reaction produces four industrially significant nitroalkanes: nitromethane, nitroethane, 1-nitropropane, and 2-nitropropane. The reaction involves free radicals, such as CH 3 CH 2 CH 2 O., which arise via homolysis of the corresponding ...
K b & K f [1] Lauric acid: 298.9 44 –3.9 Acetic acid: 1.04 117.9 3.14 16.6 –3.90 K b [1] K f [2] Acetone: 0.78 56.2 1.67 –94.8 K b [3] Benzene: 0.87 80.1 2.65 5.5 –5.12 K b & K f [2] Bromobenzene: 1.49 156.0 6.26 –30.6 Camphor: 204.0 5.95 179 –40 K f [2] Carbon disulfide: 1.29 46.2 2.34 –111.5 –3.83 Carbon tetrachloride: 1.58 76 ...
This page contains tables of azeotrope data for various binary and ternary mixtures of solvents. The data include the composition of a mixture by weight (in binary azeotropes, when only one fraction is given, it is the fraction of the second component), the boiling point (b.p.) of a component, the boiling point of a mixture, and the specific gravity of the mixture.
Nitropropane may refer to: 1-Nitropropane; 2-Nitropropane This page was last edited on 16 May 2022, at 02:06 (UTC). Text is available under the Creative ...
C 4 H 8 O 2: 1,4-Dioxane: 123-91-1 C 2 H 6 O: ethanol: 64-17-5 CH 3 CH 2 NH 2: ethylamine: 75-04-7 C 2 H 6 O 2: ethylene glycol: 107-21-1 HCOOH: formic acid: 64-18-6 C 5 H 6 O 2: furfuryl alcohol: 98-00-0 C 3 H 8 O 3: glycerol: 56-81-5 CH 3 OH: methanol: 67-56-1 CH 3 N(C 2 H 4 OH) 2: methyl diethanolamine: 105-59-9 CH 3 NC: methyl isocyanide ...
With water and a protic acid such as sulfuric acid as the reaction medium and formaldehyde the reaction product is a 1,3-diol (3). When water is absent, the cationic intermediate loses a proton to give an allylic alcohol (4). With an excess of formaldehyde and a low reaction temperature the reaction product is a dioxane (5).