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The Rüchardt experiment, [1] [2] [3] invented by Eduard Rüchardt, is a famous experiment in thermodynamics, which determines the ratio of the molar heat capacities of a gas, i.e. the ratio of (heat capacity at constant pressure) and (heat capacity at constant volume) and is denoted by (gamma, for ideal gas) or (kappa, isentropic exponent, for real gas).
The classical equipartition theorem predicts that the heat capacity ratio (γ) for an ideal gas can be related to the thermally accessible degrees of freedom (f) of a molecule by = +, =. Thus we observe that for a monatomic gas, with 3 translational degrees of freedom per atom: γ = 5 3 = 1.6666 … , {\displaystyle \gamma ={\frac {5}{3}}=1. ...
thermal conductivity (usually a lowercase Latin ) electrical conductivity of a solution; thermal diffusivity; a spring constant (usually a lowercase Latin ) the heat capacity ratio in thermodynamics (usually ) the receptor which dynorphins have the highest affinity for in pharmacology [1]
In 1780, Antoine Lavoisier used the heat released by the respiration of a guinea pig to melt snow surrounding his apparatus, showing that respiratory gas exchange is a form of combustion, similar to the burning of a candle. [2] Lavoisier named this apparatus 'calorimeter', based on both Greek and Latin roots.
Calorimetry requires that a reference material that changes temperature have known definite thermal constitutive properties. The classical rule, recognized by Clausius and Kelvin, is that the pressure exerted by the calorimetric material is fully and rapidly determined solely by its temperature and volume; this rule is for changes that do not involve phase change, such as melting of ice.
Heat capacity is a measurable physical quantity equal to the ratio of the heat added to an object to the resulting temperature change. [76] The molar heat capacity is the heat capacity per unit amount (SI unit: mole) of a pure substance, and the specific heat capacity, often called simply specific heat, is the heat capacity per unit mass of a ...
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These two values are usually denoted by and , respectively; their quotient = / is the heat capacity ratio. The term specific heat may also refer to the ratio between the specific heat capacities of a substance at a given temperature and of a reference substance at a reference temperature, such as water at 15 °C; [5] much in the fashion of ...