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Autoxidation (sometimes auto-oxidation) refers to oxidations brought about by reactions with oxygen at normal temperatures, without the intervention of flame or electric spark. [1] The term is usually used to describe the gradual degradation of organic compounds in air at ambient temperatures.
Triphenylmethane or triphenyl methane (sometimes also known as Tritan), is the hydrocarbon with the formula (C 6 H 5) 3 CH. This colorless solid is soluble in nonpolar organic solvents and not in water. Triphenylmethane is the basic skeleton of many synthetic dyes called triarylmethane dyes, many of them are pH indicators, and some display ...
The general structure of an organic peroxide. In organic chemistry, organic peroxides are organic compounds containing the peroxide functional group (R−O−O−R′).If the R′ is hydrogen, the compounds are called hydroperoxides, which are discussed in that article.
After the German chemist August Kekulé and his Belgian student Antoine Paul Nicolas Franchimont (1844–1919) first synthesized triphenylmethane in 1872, [2] the Russian doctoral student Walerius Hemilian (1851–1914) first synthesized triphenylmethanol in 1874 by reacting triphenylmethyl bromide with water as well as by oxidizing triphenylmethane.
The best test for autoxidation (oxidative rancidity) is determination of the peroxide value. Peroxides are intermediates in the autoxidation reaction. Autoxidation is a free radical reaction involving oxygen that leads to deterioration of fats and oils which form off-flavours and off-odours. Peroxide value, concentration of peroxide in an oil ...
For many polymers the general autoxidation mechanism is a reasonable approximation of the underlying chemistry. The process is autocatalytic, generating increasing numbers of radicals and reactive oxygen species.
Triphenylmethanethiol is an organosulfur compound with the formula (C 6 H 5) 3 CSH. It is the thiol derivative of the bulky substituent triphenylmethyl (called trityl). [1] [2]The compound forms a number of unusual derivatives that are more stable than less bulky analogues.
The radical was discovered by Moses Gomberg in 1900 at the University of Michigan. [9] [10] [11] He tried to prepare hexaphenylethane from triphenylmethyl chloride and zinc in benzene in a Wurtz reaction and found that the product, based on its behaviour towards iodine and oxygen, was far more reactive than anticipated.