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Liquid nitrogen is a compact and readily transported source of dry nitrogen gas, as it does not require pressurization. Further, its ability to maintain temperatures far below the freezing point of water, specific heat of 1040 J ⋅kg -1 ⋅K -1 and heat of vaporization of 200 kJ⋅kg -1 makes it extremely useful in a wide range of applications ...
Nitrogen is a colourless, odourless, and relatively inert diatomic gas with a density of 1.251 × 10 −3 g/cm 3 (marginally heavier than air). It condenses to a colourless liquid at −195.795 °C and freezes into an ice- or snow-like solid at −210.00 °C.
Because the liquid-to-gas expansion ratio of nitrogen is 1:694 at 20 °C, a tremendous amount of force can be generated if liquid nitrogen is rapidly vaporised in an enclosed space. In an incident on January 12, 2006, at Texas A&M University , the pressure-relief devices of a tank of liquid nitrogen were malfunctioning and later sealed.
The chemical element nitrogen is one of the most abundant elements in the universe and can form many compounds. It can take several oxidation states; but the most common oxidation states are -3 and +3. Nitrogen can form nitride and nitrate ions. It also forms a part of nitric acid and nitrate salts.
A space-filling model of the diatomic molecule dinitrogen, N 2. Diatomic molecules (from Greek di- 'two') are molecules composed of only two atoms, of the same or different chemical elements. If a diatomic molecule consists of two atoms of the same element, such as hydrogen (H 2) or oxygen (O 2), then it is said to be homonuclear.
The bond order of diatomic nitrogen is three, and it is a diamagnetic molecule. [12] The bond order for dinitrogen (1σ g 2 1σ u 2 2σ g 2 2σ u 2 1π u 4 3σ g 2) is three because two electrons are now also added in the 3σ MO. The MO diagram correlates with the experimental photoelectron spectrum for nitrogen. [19]
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Nitro compounds are explosive because although the diatomic form of nitrogen is very stable—that is, the triple bond that holds N 2 together is very strong, and therefore has a great deal of bond energy—the nitro compounds themselves are unstable, as the bonds between nitrogen atoms and other atoms in nitro compounds are weak by comparison.