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A standard procedure for the preparation of peresters is the acylation of tert-butyl hydroperoxide with benzoyl chloride. [6] In the reaction a large excess of tert-butyl hydroperoxide is used and the hydrogen chloride formed is removed in vacuo whereby a virtually quantitative yield is obtained. Synthesis of tert-butylperoxybenzoate
tert-Butyl peroxybenzoate; Zingerone (also called vanillylacetone) Methoxyeugenol This page was last edited on 25 September 2024, at 13:44 ...
The Kharasch–Sosnovsky reaction is a method that involves using a copper or cobalt salt as a catalyst to oxidize olefins at the allylic position, subsequently condensing a peroxy ester (e.g. tert-Butyl peroxybenzoate) or a peroxide resulting in the formation of allylic benzoates or alcohols via radical oxidation. [1]
Chemical name CAS Number Prohibitions Acetyl acetone peroxide: 37187-22-7 > 9% by mass active oxygen: Acetyl benzoyl peroxide: 644-31-5 solid, or > 40% in solution Ascaridole: 512-85-6 (organic peroxide) tert-Butyl hydroperoxide: 75-91-2 > 90% in solution (aqueous) Di-(1-naphthoyl)peroxide: 29903-04-6 Diacetyl peroxide: 110-22-5 solid, or > 25% ...
The effect of the tert-butyl group on the progress of a chemical reaction is called the Thorpe–Ingold effect illustrated in the Diels-Alder reaction below. Compared to a hydrogen substituent, the tert-butyl substituent accelerates the reaction rate by a factor of 240. [2] tert-Butyl effect. The tert-butyl effect is an example of steric hindrance.
N-tert-butyl-phenoxypropanolamines (24 P) Pages in category " Tert -butyl compounds" The following 200 pages are in this category, out of approximately 203 total.
tert-Butyl alcohol is used as a solvent, ethanol denaturant, paint remover ingredient, and gasoline octane booster and oxygenate.It is a chemical intermediate used to produce methyl tert-butyl ether (MTBE) and ethyl tert-butyl ether (ETBE) by reaction with methanol and ethanol, respectively, and tert-butyl hydroperoxide (TBHP) by reaction with hydrogen peroxide.
tert-Butyl hydroperoxide (tBuOOH) is the organic compound with the formula (CH 3) 3 COOH. It is one of the most widely used hydroperoxides in a variety of oxidation processes, like the Halcon process. [3] It is normally supplied as a 69–70% aqueous solution.