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The Castner–Kellner process is a method of electrolysis on an aqueous alkali chloride solution (usually sodium chloride solution) to produce the corresponding alkali hydroxide, [1] invented by American Hamilton Castner and Austrian Carl Kellner in the 1890s.
Faraday discovered that when the same amount of electric current is passed through different electrolytes connected in series, the masses of the substances deposited or liberated at the electrodes are directly proportional to their respective chemical equivalent/equivalent weight (E). [3]
In chemistry and manufacturing, electrolysis is a technique that uses direct electric current (DC) to drive an otherwise non-spontaneous chemical reaction. Electrolysis is commercially important as a stage in the separation of elements from naturally occurring sources such as ores using an electrolytic cell .
Important examples of electrolysis are the decomposition of water into hydrogen and oxygen, and of bauxite into aluminium and other chemicals. Electroplating (e.g. of Copper, Silver, Nickel or Chromium) is done using an electrolytic cell. Electrolysis is a technique that uses a direct electric current (DC). [citation needed]
Important examples of electrolysis are the decomposition of water into hydrogen and oxygen, and bauxite into aluminum and other chemicals. Electroplating (e.g., of copper, silver, nickel, or chromium) is done using an electrolytic cell. Electrolysis is a technique that uses a direct electric current (DC).
A well-known electrosynthesis is the Kolbe electrolysis, in which two carboxylic acids decarboxylate, and the remaining structures bond together: A variation is called the non-Kolbe reaction when a heteroatom (nitrogen or oxygen) is present at the α-position. The intermediate oxonium ion is trapped by a nucleophile, usually solvent.
Proton exchange membrane (PEM) electrolysis is the electrolysis of water in a cell equipped with a solid polymer electrolyte (SPE) [3] that is responsible for the conduction of protons, separation of product gases, and electrical insulation of the electrodes. The PEM electrolyzer was introduced to overcome the issues of partial load, low ...
Considering the industrial production of hydrogen, and using current best processes for water electrolysis (PEM or alkaline electrolysis) which have an effective electrical efficiency of 70–80%, [68] [73] [74] producing 1 kg of hydrogen (which has a specific energy of 143 MJ/kg) requires 50–55 kW⋅h (180–200 MJ) of electricity.