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According to some authors, organyl derivatives of acidic hydrogen of other acids are esters as well (e.g. amides), but not according to the IUPAC. [ 1 ] An example of an ester formation is the substitution reaction between a carboxylic acid ( R−C(=O)−OH ) and an alcohol (R'OH), forming an ester ( R−C(=O)−O−R' ), where R and R′ are ...
Esters derived from more complex carboxylic acids are, on the other hand, more frequently named using the systematic IUPAC name, based on the name for the acid followed by the suffix -oate. For example, the ester hexyl octanoate, also known under the trivial name hexyl caprylate , has the formula CH 3 (CH 2 ) 6 CO 2 (CH 2 ) 5 CH 3 .
The systematic IUPAC name is not always the preferred IUPAC name, for example, lactic acid is a common, and also the preferred, name for what systematic rules call 2-hydroxypropanoic acid. This list is ordered by the number of carbon atoms in a carboxylic acid.
For esters such as ethyl acetate (CH 3 COOCH 2 CH 3), ethyl formate (HCOOCH 2 CH 3) or dimethyl phthalate that are based on common acids, IUPAC recommends use of these established names, called retained names. The "-oate" changes to "-ate."
A notation specific for fatty acids with unbranched chain, that is as precise as the IUPAC one but easier to parse, is a code of the form "{N}:{D} cis-{CCC} trans-{TTT}", where {N} is the number of carbons (including the carboxyl one), {D} is the number of double bonds, {CCC} is a list of the positions of the cis double bonds, and {TTT} is a ...
For organic compounds containing heteroatoms (other than C and H), the list of unsaturated groups is long but some common types are: carbonyl, e.g. ketones, aldehydes, esters, carboxylic acids (unsaturated) vs alcohol or ether (saturated) nitrile (unsaturated) vs amine (saturated) nitro (unsaturated) vs amine (saturated)
Crotonic acid has 4 carbons, is included in croton oil, and is a trans-2-mono-unsaturated fatty acid.C 3 H 5 CO 2 H, IUPAC organization name (E)-but-2-enoic acid, trans-but-2-enoic acid, numerical representation 4:1, n-1, molecular weight 86.09, melting point 72–74 °C, boiling point 180–181 °C, specific gravity 1.027.
Glycerides, also known as acylglycerols, are esters formed from glycerol and fatty acids, and are generally very hydrophobic. [ 1 ] Glycerol has three hydroxyl functional groups , which can be esterified with one, two, or three fatty acids to form mono- , di- , and triglycerides . [ 2 ]