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Historically, the mole was defined as the amount of substance in 12 grams of the carbon-12 isotope.As a consequence, the mass of one mole of a chemical compound, in grams, is numerically equal (for all practical purposes) to the mass of one molecule or formula unit of the compound, in daltons, and the molar mass of an isotope in grams per mole is approximately equal to the mass number ...
The molar mass of atoms of an element is given by the relative atomic mass of the element multiplied by the molar mass constant, M u ≈ 1.000 000 × 10 −3 kg/mol ≈ 1 g/mol. For normal samples from Earth with typical isotope composition, the atomic weight can be approximated by the standard atomic weight [ 2 ] or the conventional atomic weight.
The International Bureau of Weights and Measures defined the mole as "the amount of substance of a system which contains as many elementary entities as there are atoms in 0.012 kilograms of carbon-12." Thus, by that definition, one mole of pure 12 C had a mass of exactly 12 g. [15] [5] The four different definitions were equivalent to within 1%.
For example, 50 g of zinc will react with oxygen to produce 62.24 g of zinc oxide, implying that the zinc has reacted with 12.24 g of oxygen (from the Law of conservation of mass): the equivalent weight of zinc is the mass which will react with eight grams of oxygen, hence 50 g × 8 g/12.24 g = 32.7 g.
The molar mass is defined as the mass of a given substance divided by the amount of the substance, and is expressed in grams per mol (g/mol). That makes the molar mass an average of many particles or molecules (potentially containing different isotopes), and the molecular mass the mass of one specific particle or molecule. The molar mass is ...
Approximate definition of a mole based on 12 grams of carbon-12. The Avogadro constant was historically derived from the old definition of the mole as the amount of substance in 12 grams of carbon-12 (12 C); or, equivalently, the number of daltons in a gram, where the dalton is defined as 1 / 12 of the mass of a 12 C atom. [8]
11.6 g of NaCl is dissolved in 100 g of water. The final mass concentration ρ(NaCl) is ρ(NaCl) = 11.6 g / 11.6 g + 100 g = 0.104 g/g = 10.4 %. The volume of such a solution is 104.3mL (volume is directly observable); its density is calculated to be 1.07 (111.6g/104.3mL) The molar concentration of NaCl in the solution is therefore
The interest stems from that accurate measurements of the unit cell volume, atomic weight and mass density of a pure crystalline solid provide a direct determination of the Avogadro constant. [3] The CODATA recommended value for the molar volume of silicon is 1.205 883 199 (60) × 10 −5 m 3 ⋅mol −1, with a relative standard uncertainty of ...