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Lanthanum makes up 39 mg/kg of the Earth's crust, [48] [49] behind neodymium at 41.5 mg/kg and cerium at 66.5 mg/kg. Despite being among the so-called "rare earth metals", lanthanum is thus not rare at all, but it is historically so-named because it is rarer than "common earths" such as lime and magnesia, and at the time it was recognized only ...
The lanthanide contraction, i.e. the reduction in size of the Ln 3+ ion from La 3+ (103 pm) to Lu 3+ (86.1 pm), is often explained by the poor shielding of the 5s and 5p electrons by the 4f electrons.
The ionic radii of the lanthanides decrease from 103 pm (La 3+) to 86 pm (Lu 3+) in the lanthanide series, electrons are added to the 4f shell.This first f shell is inside the full 5s and 5p shells (as well as the 6s shell in the neutral atom); the 4f shell is well-localized near the atomic nucleus and has little effect on chemical bonding.
In chemistry and atomic physics, an electron shell may be thought of as an orbit that electrons follow around an atom's nucleus.The closest shell to the nucleus is called the "1 shell" (also called the "K shell"), followed by the "2 shell" (or "L shell"), then the "3 shell" (or "M shell"), and so on further and further from the nucleus.
For example, the electronic configuration of phosphorus (P) is 1s 2 2s 2 2p 6 3s 2 3p 3 so that there are 5 valence electrons (3s 2 3p 3), corresponding to a maximum valence for P of 5 as in the molecule PF 5; this configuration is normally abbreviated to [Ne] 3s 2 3p 3, where [Ne] signifies the core electrons whose configuration is identical ...
Contrary to cyclopentadienides of most other lanthanides, in Sm(C 5 H 5) 3 some C 5 H 5 rings bridge each other by forming ring vertexes η 1 or edges η 2 toward another neighboring samarium, thus creating polymeric chains. [24] The chloroderivative Sm(C 5 H 5) 2 Cl has a dimer structure, which is more accurately expressed as (η(5)−C 5 H 5 ...
This effect is overwhelmed when the atom is positively ionised; thus Ce 2+ on its own has instead the regular configuration [Xe]4f 2, although in some solid solutions it may be [Xe]4f 1 5d 1. [11] Most lanthanides can use only three electrons as valence electrons, as afterwards the remaining 4f electrons are too strongly bound: cerium is an ...
The liquid drop model is one of the first models of nuclear structure, proposed by Carl Friedrich von Weizsäcker in 1935. [5] It describes the nucleus as a semiclassical fluid made up of neutrons and protons, with an internal repulsive electrostatic force proportional to the number of protons.