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The γ polymorph of cerium(III) sulfide adopts a cation-deficient form of the Th 3 P 4 structure. 8 out the 9 metal positions in the Th 3 P 4 structure are occupied by cerium in γ-Ce 2 S 3, with the remainder as vacancies. This composition can be represented by the formula Ce 2.667 0.333 S 4.
Cerium sulfide forms yellow crystalline solid of cubic syngony crystals, space group Fm3m, cell parameter a = 0.5780 nm, Z = 4, of NaCl-type structure. [citation needed] The compound melts congruently at a temperature of 2450 °C.
Cerium(IV) sulfate, also called ceric sulfate, is an inorganic compound. It exists as the anhydrous salt Ce(SO 4) 2 as well as a few hydrated forms: Ce(SO 4) 2 (H 2 O) x, with x equal to 4, 8, or 12. These salts are yellow to yellow/orange solids that are moderately soluble in water and dilute acids.
Cerium(IV) oxide ("ceria") has the fluorite structure, similarly to the dioxides of praseodymium and terbium. Ceria is a nonstoichiometric compound, meaning that the real formula is CeO 2−x, where x is about 0.2. Thus, the material is not perfectly described as Ce(IV). Ceria reduces to cerium(III) oxide with hydrogen gas. [3]
Cerium(III) sulfate is a hygroscopic white solid, which begins to decompose above 600°C. It has a monoclinic crystal structure. Cerium(III) sulfate tetrahydrate is a white solid that releases its water of crystallisation at 220 °C. It has (like the white octahydrate) a monoclinic crystal structure with the space group P2 1 /c (space group 14).
Cerium content in the soil varies between 2 and 150 ppm, with an average of 50 ppm; seawater contains 1.5 parts per trillion of cerium. [38] Cerium occurs in various minerals, but the most important commercial sources are the minerals of the monazite and bastnäsite groups, where it makes up about half of the lanthanide content. Monazite-(Ce ...
structure of (C 5 (CH 3) 4 H) 3 Ce.Color code: green = Ce, gray = C, white = H. Organocerium chemistry is the science of organometallic compounds that contain one or more chemical bond between carbon and cerium.
Ammonium cerium(IV) sulfate is an inorganic compound with the formula (NH 4) 4 Ce(SO 4) 4 ·2H 2 O. It is an orange-colored solid. It is an orange-colored solid. It is a strong oxidant, the potential for reduction is about +1.44V.