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The electron mobility is defined by the equation: =. where: E is the magnitude of the electric field applied to a material,; v d is the magnitude of the electron drift velocity (in other words, the electron drift speed) caused by the electric field, and
The van Deemter equation is a hyperbolic function that predicts that there is an optimum velocity at which there will be the minimum variance per unit column length and, thence, a maximum efficiency. The van Deemter equation was the result of the first application of rate theory to the chromatography elution process.
The equation predicts that for short range interactions, the equilibrium velocity distribution will follow a Maxwell–Boltzmann distribution. To the right is a molecular dynamics (MD) simulation in which 900 hard sphere particles are constrained to move in a rectangle.
One particle: N particles: One dimension ^ = ^ + = + ^ = = ^ + (,,) = = + (,,) where the position of particle n is x n. = + = = +. (,) = /.There is a further restriction — the solution must not grow at infinity, so that it has either a finite L 2-norm (if it is a bound state) or a slowly diverging norm (if it is part of a continuum): [1] ‖ ‖ = | |.
The formula for evaluating the drift velocity of charge carriers in a material of constant cross-sectional area is given by: [1] =, where u is the drift velocity of electrons, j is the current density flowing through the material, n is the charge-carrier number density, and q is the charge on the charge-carrier.
Equation [3] involves the average velocity v + v 0 / 2 . Intuitively, the velocity increases linearly, so the average velocity multiplied by time is the distance traveled while increasing the velocity from v 0 to v, as can be illustrated graphically by plotting velocity against time as a straight line graph. Algebraically, it follows ...
Once the particle is moving in the drift direction, the magnetic field deflects it back against the external force, so that the average acceleration in the direction of the force is zero. There is, however, a one-time displacement in the direction of the force equal to ( f / m ) ω c −2 , which should be considered a consequence of the ...
In other words, the electrical mobility of the particle is defined as the ratio of the drift velocity to the magnitude of the electric field: =. For example, the mobility of the sodium ion (Na + ) in water at 25 °C is 5.19 × 10 −8 m 2 /(V·s) . [ 1 ]