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The onset of thermal degradation dictates the maximum temperature at which a polymer can be used. It is an important limitation in how the polymer is manufactured and processed. For instance, polymers become less viscous at higher temperatures which makes injection moulding easier and faster, but thermal degradation places a ceiling temperature ...
Crystallization affects optical, mechanical, thermal and chemical properties of the polymer. The degree of crystallinity is estimated by different analytical methods and it typically ranges between 10 and 80%, with crystallized polymers often called "semi-crystalline". The properties of semi-crystalline polymers are determined not only by the ...
Unlike classical polymer melts, whose flow properties are largely dependent on friction between monomers, vitrimers become a viscoelastic fluid because of exchange reactions at high temperatures as well as monomer friction. [11] These two processes have different activation energies, resulting in a wide
Polymer degradation is the reduction in the physical properties of a polymer, such as strength, caused by changes in its chemical composition. Polymers and particularly plastics are subject to degradation at all stages of their product life cycle , including during their initial processing, use, disposal into the environment and recycling. [ 1 ]
Perfectly isotactic PP has a melting point of 171 °C (340 °F). Commercial isotactic PP has a melting point that ranges from 160 to 166 °C (320 to 331 °F), depending on atactic material and crystallinity. Syndiotactic PP with a crystallinity of 30% has a melting point of 130 °C (266 °F). [8] Below 0 °C, PP becomes brittle. [9]
This interferes with crystallization and lowers the polymer's melting temperature. In general, such PET is known as PETG or PET-G (polyethylene terephthalate glycol-modified). It is a clear amorphous thermoplastic that can be injection-molded, sheet-extruded or extruded as filament for 3D printing .
PTFE is a thermoplastic polymer, which is a white solid at room temperature, with a density of about 2200 kg/m 3 and a melting point of 600 K (327 °C; 620 °F). [26] It maintains high strength, toughness and self-lubrication at low temperatures down to 5 K (−268.2 °C; −450.7 °F), and good flexibility at temperatures above 194 K (−79.15 ...
Although it is thermoplastic, polyacrylonitrile does not melt under normal conditions. It degrades before melting. It melts above 300 °C if the heating rates are 50 degrees per minute or above. [12] Glass transition temperature is around 95 °C and fusion temperature is at 322 °C.