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Ethyl nitrate is the ethyl ester of nitric acid and has the chemical formula C 2 H 5 N O 3.It is a colourless, volatile, explosive, and extremely flammable liquid. It is used in organic synthesis with use as a nitrating agent and as an intermediate in the preparation of some drugs, dyes, and perfumes. [1]
Methemoglobinemia is the primary toxic effect of ethyl nitrite. [5] Due to ethyl nitrite's high volatility and faint smell, in the presence of ethyl nitrite vapors, it is easy to breath a high dose of it without realizing, resulting in methemoglobinemia, [ 6 ] which may or may not be severe, or even fatal .
Likewise pyrrolidine is a substrate for ethyl nitrite. [6] Alkyl nitrites are also used in the formation of oximes with the stronger carbon acids and acid or base catalysis for example in the reaction of 2-butanone, ethyl nitrite and hydrochloric acid forming the oxime, [7] the similar reaction with phenacyl chloride, [8] or the reaction of ...
Methyl nitrate is a very strong explosive with a detonation velocity of 6,300 m/s, [8] like nitroglycerin, ethylene glycol dinitrate, and other nitrate esters. The sensitivity of methyl nitrate to initiation by detonation is among the greatest known, with even a number one blasting cap , the lowest power available, producing a near full ...
Ethylammonium nitrate can be produced by heating ethyl nitrate with an alcoholic solution of ammonia [8] or by reacting ethylamine with concentrated nitric acid. [6] It has a relatively low viscosity of 0.28 poise or 0.028 Pa·s at 25 °C and therefore a high electrical conductivity of about 20 mS·cm −1 at 25 °C.
One of the main cetane improver additives manufactured today is 2-ethylhexyl nitrate (CAS n°: 27247-96-7) [1] which starts to decompose at 130 °C. 2-ethylhexyl nitrate is the result of the reaction of 2-ethylhexanol and nitric acid.
Creatine supplements are marketed in ethyl ester, gluconate, monohydrate, and nitrate forms. [40] Creatine supplementation for sporting performance enhancement is considered safe for short-term use but there is a lack of safety data for long term use, or for use in children and adolescents. [41] Some athletes choose to cycle on and off creatine ...
Note that nitrogen is a better nucleophile than oxygen and most nitrites would react via an S N 2-like mechanism and the major product would be nitromethane. For example, sodium and potassium nitrite reacting with iodomethane would produce mostly nitromethane, with methyl nitrite as the minor product.