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The ability of the system to be readily deformed above its glass transition temperature allows polystyrene (and thermoplastic polymers in general) to be readily softened and molded upon heating. Extruded polystyrene is about as strong as an unalloyed aluminium but much more flexible and much less dense (1.05 g/cm 3 for polystyrene vs. 2.70 g/cm ...
Temperature-responsive polymers or thermoresponsive polymers are polymers that exhibit drastic and discontinuous changes in their physical properties with temperature. [1] The term is commonly used when the property concerned is solubility in a given solvent , but it may also be used when other properties are affected.
In one copolymer, the monomers can be almost perfectly alternating. [1] but (random) copolymerisation with less than 50% maleic anhydride content is also possible. [2] The polymer is formed by a radical polymerization, using an organic peroxide as the initiator. The main characteristics of SMA copolymer are its transparent appearance, high heat ...
It is one of the most developed methods in chain-growth polymerization. Currently, most polymers in our daily life are synthesized by free radical polymerization, including polyethylene, polystyrene, polyvinyl chloride, polymethyl methacrylate, polyacrylonitrile, polyvinyl acetate, styrene butadiene rubber, nitrile rubber, neoprene, etc.
Copolymerization is particularly useful in tuning the glass transition temperature, which is important in the operating conditions of polymers; it is assumed that each monomer occupies the same amount of free volume whether it is in a copolymer or homopolymer, so the glass transition temperature (T g) falls between the values for each ...
Living polymerization: A chain polymerization from which chain transfer and chain termination are absent.. Note: In many cases, the rate of chain initiation is fast compared with the rate of chain propagation, so that the number of kinetic-chain carriers is essentially constant throughout the polymerization.
Styrene acrylonitrile resin (SAN) is a copolymer plastic consisting of styrene and acrylonitrile. It is widely used in place of polystyrene owing to its greater thermal resistance. The chains of between 70 and 80% by weight styrene and 20 to 30% acrylonitrile. [ 1 ]
Left: individual linear polymer chains Right: Polymer chains which have been cross linked to give a rigid 3D thermoset polymer. In materials science, a thermosetting polymer, often called a thermoset, is a polymer that is obtained by irreversibly hardening ("curing") a soft solid or viscous liquid prepolymer (). [1]
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