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A typical reaction with silver nitrate is to suspend a rod of copper in a solution of silver nitrate and leave it for a few hours. The silver nitrate reacts with copper to form hairlike crystals of silver metal and a blue solution of copper nitrate: 2 AgNO 3 + Cu → Cu(NO 3) 2 + 2 Ag. Silver nitrate decomposes when heated:
Solution of sodium polysulfide 2.5%, items must be submerged in the solution after color developing, wash, dry and wax or varnish colored object. [27] Brown for copper. Items are boiled in at least 3-day-old water solution of 12% copper sulfate, after color being developed, the material is washed, dried and waxed or varnished. [27] Black for iron
The solution is then treated with various reagents to test for reactions characteristic of certain ions, which may cause color change, precipitation and other visible changes. [ 1 ] [ 2 ] Qualitative inorganic analysis is that branch or method of analytical chemistry which seeks to establish the elemental composition of inorganic compounds ...
Silver acetylide can be produced by passing acetylene gas through a solution of silver nitrate: [3] 2 AgNO 3 (aq) + C 2 H 2 (g) → Ag 2 C 2 (s) + 2 HNO 3 (aq) The reaction product is a greyish to white precipitate. This is the same synthesis from Berthelot in which he first found silver acetylide in 1866. [4]
Silver sulfate precipitates as a solid when an aqueous solution of silver nitrate is treated with sulfuric acid: 2 AgNO 3 + H 2 SO 4 → Ag 2 SO 4 + 2 HNO 3. It is purified by recrystallization from concentrated sulfuric acid, a step that expels traces of nitrate. [7] Silver sulfate and anhydrous sodium sulfate adopt the same structure. [8]
Silver carbonate can be prepared by combining aqueous solutions of sodium carbonate with a deficiency of silver nitrate. [8] 2 AgNO 3 (aq) + Na 2 CO 3 (aq) → Ag 2 CO 3 (s) + 2 NaNO 3 (aq) Freshly prepared silver carbonate is colourless, but the solid quickly turns yellow. [9]
Silver nitrite is much less soluble in water than silver nitrate, and a solution of silver nitrate will readily precipitate silver nitrite upon addition of sodium nitrite: AgNO 3 (aq) + NaNO 2 (s) → NaNO 3 (aq) + AgNO 2 (precipitate) Alternatively, it can be produced by the reaction between silver sulfate and barium nitrite.
When the pH of the solution is increased by adding an alkaline solution to it, the extent of hydrolysis increases. Measurements of pH or colour change are used to derive the equilibrium constant for the reaction. Further hydrolysis may occur, producing dimeric, trimeric or polymeric species containing hydroxy- or oxy- groups.