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General reaction scheme for the S N 1 reaction. The leaving group is denoted "X", and the nucleophile is denoted "Nu–H". The unimolecular nucleophilic substitution (S N 1) reaction is a substitution reaction in organic chemistry.
With standard S N 1 reaction conditions the reaction outcome is retention via a competing S N i mechanism and not racemization and with pyridine added the result is again inversion. [5] [3] S N i reaction mechanism Sn1 occurs in tertiary carbon while Sn2 occurs in primary carbon
Sigmatropic rearrangements are concisely described by an order term [i,j], which is defined as the migration of a σ-bond adjacent to one or more π systems to a new position (i−1) and (j−1) atoms removed from the original location of the σ-bond. [3]
Walden inversion is the inversion of a stereogenic center in a chiral molecule in a chemical reaction. Since a molecule can form two enantiomers around a stereogenic center, the Walden inversion converts the configuration of the molecule from one enantiomeric form to the other.
Evolutionary epistemology of theories assumes that scientific theories develop through variation and selection; Memetics is a theory of the variation, transmission, and selection of cultural items, such as ideas, fashions, and traditions; Dual inheritance theory a framework for cultural evolution developed largely independently of memetics
The mediaeval great chain of being as a staircase, implying the possibility of progress: [1] Ramon Lull's Ladder of Ascent and Descent of the Mind, 1305. Alternatives to Darwinian evolution have been proposed by scholars investigating biology to explain signs of evolution and the relatedness of different groups of living things.
The timeline of the evolutionary history of life represents the current scientific theory outlining the major events during the development of life on planet Earth. Dates in this article are consensus estimates based on scientific evidence , mainly fossils .
A scenario is a set of related concepts pertinent to the origin of life (abiogenesis), such as the iron-sulfur world.Many alternative abiogenesis scenarios have been proposed by scientists in a variety of fields from the 1950s onwards in an attempt to explain how the complex mechanisms of life could have come into existence.