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Data in the table above is given for water–steam equilibria at various temperatures over the entire temperature range at which liquid water can exist. Pressure of the equilibrium is given in the second column in kPa. The third column is the heat content of each gram of the liquid phase relative to water at 0 °C.
[12] [13] For example, for a single component, a 3D Cartesian coordinate type graph can show temperature (T) on one axis, pressure (p) on a second axis, and specific volume (v) on a third. Such a 3D graph is sometimes called a p–v–T diagram. The equilibrium conditions are shown as curves on a curved surface in 3D with areas for solid ...
The main feature of thermodynamic diagrams is the equivalence between the area in the diagram and energy. When air changes pressure and temperature during a process and prescribes a closed curve within the diagram the area enclosed by this curve is proportional to the energy which has been gained or released by the air.
However, the liquid–vapor boundary terminates in an endpoint at some critical temperature T c and critical pressure p c. This is the critical point. The critical point of water occurs at 647.096 K (373.946 °C; 705.103 °F) and 22.064 megapascals (3,200.1 psi; 217.75 atm; 220.64 bar). [3]
Heat of vaporization of water from melting to critical temperature. Water has a very high specific heat capacity of 4184 J/(kg·K) at 20 °C (4182 J/(kg·K) at 25 °C)—the second-highest among all the heteroatomic species (after ammonia), as well as a high heat of vaporization (40.65 kJ/mol or 2268 kJ/kg at the normal boiling point), both of ...
Temperature-dependency of the heats of vaporization for water, methanol, benzene, and acetone. In thermodynamics, the enthalpy of vaporization (symbol ∆H vap), also known as the (latent) heat of vaporization or heat of evaporation, is the amount of energy that must be added to a liquid substance to transform a quantity of that substance into a gas.
In liquids, viscous forces are caused by molecules exerting attractive forces on each other across layers of flow. Increasing temperature results in a decrease in viscosity because a larger temperature means particles have greater thermal energy and are more easily able to overcome the attractive forces binding them together.
In thermodynamics, a temperature–entropy (T–s) diagram is a thermodynamic diagram used to visualize changes to temperature (T ) and specific entropy (s) during a thermodynamic process or cycle as the graph of a curve. It is a useful and common tool, particularly because it helps to visualize the heat transfer during a process.