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Magnesium chloride is an inorganic compound with the formula Mg Cl 2.It forms hydrates MgCl 2 ·nH 2 O, where n can range from 1 to 12. These salts are colorless or white solids that are highly soluble in water.
Since magnesium nitrate has a high affinity for water, heating the hexahydrate does not result in the dehydration of the salt, but rather its decomposition into magnesium oxide, oxygen, and nitrogen oxides: 2 Mg(NO 3) 2 → 2 MgO + 4 NO 2 + O 2. The absorption of these nitrogen oxides in water is one possible route to synthesize nitric acid.
The anhydrous sulfate is produced by heating the hydrates above 330 °C. X-ray crystallography measurements show that NiSO 4 ·6H 2 O consists of the octahedral [Ni(H 2 O) 6] 2+ ions. These ions in turn are hydrogen bonded to sulfate ions. [5] Dissolution of the salt in water gives solutions containing the aquo complex [Ni(H 2 O) 6] 2+.
A hydrate that has lost water is referred to as an anhydride; the remaining water, if any exists, can only be removed with very strong heating. A substance that does not contain any water is referred to as anhydrous. Some anhydrous compounds are hydrated so easily that they are said to be hygroscopic and are used as drying agents or desiccants.
Nickel nitrate is the inorganic compound Ni(NO 3) 2 or any hydrate thereof. In the hexahydrate, the nitrate anions are not bonded to nickel. Other hydrates have also been reported: Ni(NO 3) 2. 9H 2 O, Ni(NO 3) 2. 4H 2 O, and Ni(NO 3) 2. 2H 2 O. [3] It is prepared by the reaction of nickel oxide with nitric acid:
Only four of the six water molecules in the formula is bound to the nickel, and the remaining two are water of crystallization, so the formula of nickel(II) chloride hexahydrate is [NiCl 2 (H 2 O) 4]·2H 2 O. [9] Cobalt(II) chloride hexahydrate has a similar structure. The hexahydrate occurs in nature as the very rare mineral nickelbischofite.
Zinc nitrate is usually prepared by dissolving zinc metal, zinc oxide, or related materials in nitric acid: Zn + 2 HNO 3 → Zn(NO 3) 2 + H 2 ZnO + 2 HNO 3 → Zn(NO 3) 2 + H 2 O. These reactions are accompanied by the hydration of the zinc nitrate.
The crystal unit of the solid hexahydrate CoCl 2 •6 H 2 O contains the neutral molecule trans-CoCl 2 (H 2 O) 4 and two molecules of water of crystallization. [8] This species dissolves readily in water and alcohol. The anhydrous salt is hygroscopic and the hexahydrate is deliquescent. [citation needed] The dihydrate, CoCl 2 (H 2 O) 2, is a ...
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