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3 NaClO → NaClO 3 + 2 NaCl. This reaction is accelerated at temperatures above about 60 °C. Other reactions occur, such as the self-ionization of water and the decomposition of hypochlorite at the cathode, the rate of the latter depends on factors such as diffusion and the surface area of the cathode in contact with the electrolyte. [9]
The pH of a sodium chloride solution remains ≈7 due to the extremely weak basicity of the Cl − ion, which is the conjugate base of the strong acid HCl. In other words, NaCl has no effect on system pH [32] in diluted solutions where the effects of ionic strength and activity coefficients are negligible.
Chloride cycle anion ion-exchange dealkalizers remove alkalinity from water. Chloride cycle dealkalizers operate similar to sodium cycle cation water softeners . Like water softeners, dealkalizers contain ion-exchange resins that are regenerated with a concentrated salt ( brine ) solution - NaCl.
The solution travels to a tank that separates the hydrogen gas based on its low density. [1] Only water and sodium chloride are used. The simplified chemical reaction is: NaCl + H 2 O + energy → NaOCl + H 2 [citation needed] That is, energy is added to sodium chloride (table salt) in water, producing sodium hypochlorite and hydrogen gas.
The term cycle is used because aside of water, hydrogen and oxygen, the chemical compounds used in these processes are continuously recycled. If work is partially used as an input, the resulting thermochemical cycle is defined as a hybrid one.
If the two solutions have hydrogen ions and hydroxide ions as the counterions, they will react with one another in what is called an acid–base reaction or a neutralization reaction to form water. [12] Alternately the counterions can be chosen to ensure that even when combined into a single solution they will remain soluble as spectator ions. [11]
When dissolved in water, chlorine converts to an equilibrium mixture of chlorine, hypochlorous acid (HOCl), and hydrochloric acid (HCl): Cl 2 + H 2 O ⇌ HOCl + HCl. In acidic solution, the major species are Cl 2 and HOCl, whereas in alkaline solution, effectively only ClO − (hypochlorite ion) is present.
Sodium chlorate can be used with hydrochloric acid (or also sulfuric acid and sodium chloride, the reaction of which generates HCl) to chlorinate aromatic compounds without the use of organic solvents. In this case its function is to oxidize the HCl to obtain either HOCl or Cl 2 (depending upon the pH) in-situ which are the active chlorinating ...