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The cyclic metasilicate ring Si 6 O 12− 18 is a hexamer of SiO 3 2-. Polymeric silicate anions of can exist also as long chains. In single-chain silicates, which are a type of inosilicate, tetrahedra link to form a chain by sharing two oxygen atoms each. A common mineral in this group is pyroxene. Double chain tetrahedra.
Lithium aluminium silicate mineral spodumene. Silicate minerals are rock-forming minerals made up of silicate groups. They are the largest and most important class of minerals and make up approximately 90 percent of Earth's crust. [1] [2] [3] In mineralogy, silica (silicon dioxide, SiO 2) is usually considered a silicate mineral rather than an ...
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Potassium silicate can be synthesized in the laboratory by treating silica with potassium hydroxide, according to this idealized equation: nSiO 2 + 2 KOH → K 2 O·nSiO 2 + H 2 O. These solutions are highly alkaline. Addition of acids causes the reformation of silica. K 2 SiO 3 adopts a chain or cyclic structures with interlinked SiO 2− 3 ...
Dimethyldichlorosilane (Si(CH 3) 2 Cl 2) is a key precursor to cyclic (D 3, D 4, etc.) and linear siloxanes. [5] The main route to siloxane functional group is by hydrolysis of silicon chlorides: 2 R 3 Si−Cl + H 2 O → R 3 Si−O−SiR 3 + 2 HCl. The reaction proceeds via the initial formation of silanols (R 3 Si−OH): R 3 Si−Cl + H 2 O ...
Given sufficient time, rainwater can dissolve even a highly resistant silicate-based mineral such as quartz. [13] Water breaks the bonds between atoms in the crystal: [14] The overall reaction for the dissolution of quartz results in silicic acid. SiO 2 + 2H 2 O → H 4 SiO 4. Another example of a silicate-based mineral is enstatite (MgSiO 3).
Cyclic compounds may or may not exhibit aromaticity; benzene is an example of an aromatic cyclic compound, while cyclohexane is non-aromatic. In organic chemistry, the term aromaticity is used to describe a cyclic (ring-shaped), planar (flat) molecule that exhibits unusual stability as compared to other geometric or connective arrangements of ...
Soro-silicates, involving discrete double or triple tetrahedral units, are quite rare: metasilicates involving cyclic [(SiO n 3)] 2n− units of corner-abutting tetrahedra forming a polygonal ring are also known. [15] Chain metasilicates, {SiO 2− 3} ∞, form by corner-sharing of an indefinite chain of linked SiO tetrahedra. Many differences ...