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Atmospheric pollutant concentrations expressed as mass per unit volume of atmospheric air (e.g., mg/m 3, μg/m 3, etc.) at sea level will decrease with increasing altitude because the atmospheric pressure decreases with increasing altitude. The change of atmospheric pressure with altitude can be obtained from this equation: [2]
Heating-gas-at-constant-pressure-and-constant-volume The molar gas constant (also known as the gas constant , universal gas constant , or ideal gas constant ) is denoted by the symbol R or R . It is the molar equivalent to the Boltzmann constant , expressed in units of energy per temperature increment per amount of substance , rather than ...
The standard unit is the meter cubed per kilogram (m 3 /kg or m 3 ·kg −1). Sometimes specific volume is expressed in terms of the number of cubic centimeters occupied by one gram of a substance. In this case, the unit is the centimeter cubed per gram (cm 3 /g or cm 3 ·g −1). To convert m 3 /kg to cm 3 /g, multiply by 1000; conversely ...
At IUPAC standard temperature and pressure (0 °C and 100 kPa), dry air has a density of approximately 1.2754 kg/m 3. At 20 °C and 101.325 kPa, dry air has a density of 1.2041 kg/m 3. At 70 °F and 14.696 psi, dry air has a density of 0.074887 lb/ft 3.
at each geopotential altitude, where g is the standard acceleration of gravity, and R specific is the specific gas constant for dry air (287.0528J⋅kg −1 ⋅K −1). The solution is given by the barometric formula. Air density must be calculated in order to solve for the pressure, and is used in calculating dynamic pressure for moving vehicles.
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As an example, a measured NO x concentration of 45 ppmv in a dry gas having 5 volume % O 2 is: 45 × ( 20.9 - 3 ) ÷ ( 20.9 - 5 ) = 50.7 ppmv of NO x. when corrected to a dry gas having a specified reference O 2 content of 3 volume %. Note: The measured gas concentration C m must first be corrected to a dry basis before using the above equation.
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