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  2. Lower critical solution temperature - Wikipedia

    en.wikipedia.org/wiki/Lower_critical_solution...

    A key physical factor which distinguishes the LCST from other mixture behavior is that the LCST phase separation is driven by unfavorable entropy of mixing. [18] Since mixing of the two phases is spontaneous below the LCST and not above, the Gibbs free energy change (ΔG) for the mixing of these two phases is negative below the LCST and positive above, and the entropy change ΔS = – (dΔG/dT ...

  3. Unbibium - Wikipedia

    en.wikipedia.org/wiki/Unbibium

    Unbibium, also known as element 122 or eka-thorium, is a hypothetical chemical element; it has placeholder symbol Ubb and atomic number 122. Unbibium and Ubb are the temporary systematic IUPAC name and symbol respectively, which are used until the element is discovered, confirmed, and a permanent name is decided upon.

  4. Intensive and extensive properties - Wikipedia

    en.wikipedia.org/wiki/Intensive_and_extensive...

    = 22.4 L/mol is the molar volume of an ideal gas at standard conditions for temperature and pressure [13] (being 1 bar and 273.15 K). C P , m ∘ {\displaystyle C_{P,\mathrm {m} }^{\circ }} is the standard molar heat capacity of a substance at constant pressure.

  5. Critical point (thermodynamics) - Wikipedia

    en.wikipedia.org/wiki/Critical_point...

    In the vicinity of the critical point, the physical properties of the liquid and the vapor change dramatically, with both phases becoming even more similar. For instance, liquid water under normal conditions is nearly incompressible, has a low thermal expansion coefficient, has a high dielectric constant , and is an excellent solvent for ...

  6. Molar heat capacity - Wikipedia

    en.wikipedia.org/wiki/Molar_heat_capacity

    The value obtained this way is said to be the molar heat capacity at constant volume (or isochoric) and denoted c V,m, c v,m, c v,m, etc. The value of c V,m is always less than the value of c P,m. This difference is particularly notable in gases where values under constant pressure are typically 30% to 66.7% greater than those at constant ...

  7. Partial molar property - Wikipedia

    en.wikipedia.org/wiki/Partial_molar_property

    When one mole of water is added to a large volume of water at 25 °C, the volume increases by 18 cm 3. The molar volume of pure water would thus be reported as 18 cm 3 mol −1. However, addition of one mole of water to a large volume of pure ethanol results in an increase in volume of only 14 cm 3. The reason that the increase is different is ...

  8. Phase rule - Wikipedia

    en.wikipedia.org/wiki/Phase_rule

    In thermodynamics, the phase rule is a general principle governing multi-component, multi-phase systems in thermodynamic equilibrium.For a system without chemical reactions, it relates the number of freely varying intensive properties (F) to the number of components (C), the number of phases (P), and number of ways of performing work on the system (N): [1] [2] [3]: 123–125

  9. Thermodynamic activity - Wikipedia

    en.wikipedia.org/wiki/Thermodynamic_activity

    The relative activity of a species i, denoted a i, is defined [4] [5] as: = where μ i is the (molar) chemical potential of the species i under the conditions of interest, μ o i is the (molar) chemical potential of that species under some defined set of standard conditions, R is the gas constant, T is the thermodynamic temperature and e is the exponential constant.

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