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Arsenic acid or arsoric acid is the chemical compound with the formula H 3 AsO 4. More descriptively written as AsO(OH) 3, this colorless acid is the arsenic analogue of phosphoric acid. Arsenate and phosphate salts behave very similarly. Arsenic acid as such has not been isolated, but is only found in solution, where it is largely ionized.
The arsenate is an ion with the chemical formula AsO 3− 4. [1] Bonding in arsenate consists of a central arsenic atom, with oxidation state +5, double bonded to one oxygen atom and single bonded to a further three oxygen atoms. [2] The four oxygen atoms orient around the arsenic atom in a tetrahedral geometry. [2]
Arsenic forms colorless, odorless, crystalline oxides As 2 O 3 ("white arsenic") and As 2 O 5 which are hygroscopic and readily soluble in water to form acidic solutions. Arsenic(V) acid is a weak acid and the salts are called arsenates , [ 5 ] the most common arsenic contamination of groundwater , and a problem that affects many people.
In its standard state arsine is a colorless, denser-than-air gas that is slightly soluble in water (2% at 20 °C) [1] and in many organic solvents as well. [citation needed] Arsine itself is odorless, [5] but it oxidizes in air and this creates a slight garlic or fish-like scent when the compound is present above 0.5 ppm. [6]
Disodium hydrogen arsenate is highly toxic. The salt is the conjugate base of arsenic acid. It is a white, water-soluble solid. [1] Being a diprotic acid, its acid-base properties is described by two equilibria: H 2 AsO − 4 + H 2 O ⇌ HAsO 2− 4 + H 3 O + (pK a2 = 6.94) HAsO 2− 4 + H 2 O ⇌ AsO 3− 4 + H 3 O + (pK a3 = 11.5)
With its first pK a being 9.2, As(OH) 3 is a weak acid. [4] Reactions attributed to aqueous arsenic trioxide are due to arsenous acid and its conjugate bases. Like arsenic trioxide, arsenous acid is sometimes amphoteric. For example, it reacts with hydrochloric, hydrobromic, and hydroiodic acids to produce arsenic trichloride, tribromide, and ...
Solubility in water. ... compound with the chemical formula NH 4 H 2 AsO 4. [2] [3] Synthesis. The effect of ammonia on a concentrated solution of arsenic acid: NH 3 ...
Like all arsenic-containing compounds, arsonic acids are toxic and carcinogenic to humans. [1] [2] Arsonic acid refers to H 3 As O 3, the case where the substituent is a single hydrogen atom. The other arsonic acids can simply be viewed as hydrocarbyl derivatives of this base case. Arsenic acid results when the substituent is a hydroxyl group.