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In analytical chemistry, the detection limit, lower limit of detection, also termed LOD for limit of detection or analytical sensitivity (not to be confused with statistical sensitivity), is the lowest quantity of a substance that can be distinguished from the absence of that substance (a blank value) with a stated confidence level (generally 99%).
A calibration curve plot showing limit of detection (LOD), limit of quantification (LOQ), dynamic range, and limit of linearity (LOL).. In analytical chemistry, a calibration curve, also known as a standard curve, is a general method for determining the concentration of a substance in an unknown sample by comparing the unknown to a set of standard samples of known concentration. [1]
Memorial in Jena, Germany to Ernst Karl Abbe, who approximated the diffraction limit of a microscope as = , where d is the resolvable feature size, λ is the wavelength of light, n is the index of refraction of the medium being imaged in, and θ (depicted as α in the inscription) is the half-angle subtended by the optical objective lens (representing the numerical aperture).
There are different definitions within laboratory quality control, wherein "analytical sensitivity" is defined as the smallest amount of substance in a sample that can accurately be measured by an assay (synonymously to detection limit), and "analytical specificity" is defined as the ability of an assay to measure one particular organism or ...
Dynamic range (abbreviated DR, DNR, [1] or DYR [2]) is the ratio between the largest and smallest measurable values of a specific quantity. It is often used in the context of signals, like sound and light.
The Scherrer equation, in X-ray diffraction and crystallography, is a formula that relates the size of sub-micrometre crystallites in a solid to the broadening of a peak in a diffraction pattern. It is often referred to, incorrectly, as a formula for particle size measurement or analysis.
Some of the earliest work on what would become known as Fresnel diffraction was carried out by Francesco Maria Grimaldi in Italy in the 17th century. In his monograph entitled "Light", [3] Richard C. MacLaurin explains Fresnel diffraction by asking what happens when light propagates, and how that process is affected when a barrier with a slit or hole in it is interposed in the beam produced by ...
Neutron activation analysis is a sensitive multi-element analytical technique used for both qualitative and quantitative analysis of major, minor, trace and rare elements.. NAA was discovered in 1936 by Hevesy and Levi, who found that samples containing certain rare-earth elements became highly radioactive after exposure to a source of neutrons