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Most palladium is used for catalytic converters in the automobile industry. [77] Catalytic converters are targets for thieves because they contain palladium and other rare metals. In the run up to year 2000, the Russian supply of palladium to the global market was repeatedly delayed and disrupted; for political reasons, the export quota was not ...
Natural palladium (46 Pd) is composed of six stable isotopes, 102 Pd, 104 Pd, 105 Pd, 106 Pd, 108 Pd, and 110 Pd, although 102 Pd and 110 Pd are theoretically unstable. The most stable radioisotopes are 107 Pd with a half-life of 6.5 million years, 103 Pd with a half-life of 17 days, and 100 Pd with a half-life of 3.63 days.
Palladium forms a variety of ionic, coordination, and organopalladium compounds, typically with oxidation state Pd 0 or Pd 2+. Palladium(III) compounds have also been reported. Palladium compounds are frequently used as catalysts in cross-coupling reactions such as the Sonogashira coupling and Suzuki reaction.
Naturally occurring platinum and platinum-rich alloys were known by pre-Columbian Americans for many years. [5] However, even though the metal was used by pre-Columbian peoples, the first European reference to platinum appears in 1557 in the writings of the Italian humanist Julius Caesar Scaliger (1484–1558) as a description of a mysterious metal found in Central American mines between ...
This article summarizes the world palladium production by country. This is a list of countries by palladium production in kilograms, based upon data from the United States Geological Survey. [1] In 2019, the world production of palladium totaled 210,000 kilograms—down 5% from 220,000 kg in 2018.
The palladium forms an alloy with the fission tellurium. This alloy can separate from the glass. 107 Pd is the only long-living radioactive isotope among the fission products and its beta decay has a long half life and low energy, this allows industrial use of extracted palladium without isotope separation. [9]
The use of sparteine as a ligand (Figure 2, A) [33] favors nucleopalladation at the terminal carbon to minimize steric interaction between the palladium complex and substrate. The Quinox-ligated palladium catalyst is used to favor ketone formation when substrate contains a directing group (Figure 2, B). [ 34 ]
Palladium(II) sulfate is produced by the reaction of palladium metal with a mixture of nitric acid and sulfuric acid. It can also be produced by the reaction of palladium(II) sulfide and oxygen in dimethylformamide. [1] [3] [4] [5] When anhydrous palladium(II) sulfate absorbs moisture from the air, it forms a greenish-brown dihydrate.