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Quaternary ammonium cation. The R groups may be the same or different alkyl or aryl groups. Also, the R groups may be connected. In organic chemistry, quaternary ammonium cations, also known as quats, are positively-charged polyatomic ions of the structure [NR 4] +, where R is an alkyl group, an aryl group [1] or organyl group.
In chemistry, a quaternary compound is a compound consisting of exactly four chemical elements. In another use of the term in organic chemistry , a quaternary compound is or has a cation consisting of a central positively charged atom with four substituents, especially organic ( alkyl and aryl ) groups, discounting hydrogen atoms.
The hydrogen atoms in the ammonium ion can be substituted with an alkyl group or some other organic group to form a substituted ammonium ion (IUPAC nomenclature: aminium ion). Depending on the number of organic groups, the ammonium cation is called a primary , secondary , tertiary , or quaternary .
Quaternary ammonium compounds are positively charged polyatomic ions of the structure NR 4 + with R being alkyl or aryl groups. The R groups may also be connected. The R groups may also be connected. Wikimedia Commons has media related to Quaternary ammonium compounds .
Tetramethylammonium (TMA) is the simplest quaternary ammonium cation. It has the chemical formula [Me 4 N] + and consists of four methyl groups (−CH 3, denoted Me) attached to a central nitrogen atom. The cation is isoelectronic with neopentane (Me 4 C). It is positively-charged and can only be isolated in association with a counter-ion.
It is an organic salt classified as a quaternary ammonium compound. ADBACs have three main categories of use: as a biocide, a cationic surfactant, and a phase transfer agent. [2] ADBACs are a mixture of alkylbenzyldimethylammonium chlorides, in which the alkyl group has various even-numbered alkyl chain lengths.
In organic chemistry, alkylammonium refers to cations of the formula [R 4−n NH n] +, where R = alkyl and 1≤ n ≤ 4. The cations with four alkyl substituents, i.e., [R 4 N] +, are further classified as quaternary ammonium cations and are discussed more thoroughly in the article with that title.
Tetraethylammonium (TEA) is a quaternary ammonium cation with the chemical formula [Et 4 N] +, consisting of four ethyl groups (−C 2 H 5, denoted Et) attached to a central nitrogen atom. It is a counterion used in the research laboratory to prepare lipophilic salts of inorganic anions.