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Sodium naphthalene is an organic salt with the chemical formula Na + [C 10 H 8] −. In the research laboratory, it is used as a reductant in the synthesis of organic, organometallic, and inorganic chemistry. It is usually generated in situ. When isolated, it invariably crystallizes as a solvate with ligands bound to Na +. [1]
With alkali metals, naphthalene forms the dark blue-green radical anion salts such as sodium naphthalene, Na + C 10 H − 8. The naphthalene anions are strong reducing agents. Naphthalene can be hydrogenated under high pressure in the presence of metal catalysts to give 1,2,3,4-tetrahydronaphthalene(C 10 H 12), also known as tetralin.
Naphthalenesulfonates are derivatives of sulfonic acid which contain a naphthalene functional unit. A related family of compounds are the aminonaphthalenesulfonic acids.Of commercial importance are the alkylnaphthalene sulfonates, which are used as superplasticizers in concrete.
Aminonaphthalenesulfonic acids are compounds with the composition C 10 H 6 (NH 2)(SO 3 H), being derived from naphthalene (C 10 H 8) substituted by an amino and sulfonic acid groups. These compounds are colorless solids. They are useful precursors to dyes. [1]
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Naphthalene-2-sulfonic acid undergoes many reactions, some of which are or were of commercial interest. Fusion with sodium hydroxide followed by acidification gives 2-naphthol . It is an intermediate in the formation of 2,6-, 2,7- and 1,6-naphthalene disulfonic acids as well as 1,3,6-naphthalenetrisulfonic acid.
The sulfonic acid derivatives of 1-naphthylamine are used for the preparation of azo dye.These compounds possess the important property of dyeing unmordanted cotton.. An important derivative is naphthionic acid (1-aminonaphthalene-4-sulfonic acid), which is produced by heating 1-naphthylamine and sulfuric acid to 170–180 °C in the presence of crystallized oxalic acid.
Alkylated naphthalenes are chemical compounds made by the alkylation of naphthalene or its derivatives with an olefin. These compounds are used as synthetic base oils, and are claimed to have improved oxidative stability over some conventional base oils.