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The solutions of the Schrödinger equation in polar coordinates in vacuum are thus labelled by three quantum numbers: discrete indices ℓ and m, and k varying continuously in [,): = (,) These solutions represent states of definite angular momentum, rather than of definite (linear) momentum, which are provided by plane waves ().
The Klein–Gordon equation, + =, was the first such equation to be obtained, even before the nonrelativistic one-particle Schrödinger equation, and applies to massive spinless particles. Historically, Dirac obtained the Dirac equation by seeking a differential equation that would be first-order in both time and space, a desirable property for ...
Animated wave function of a “coherent” state consisting of eigenstates n=1 and n=2. Using polar coordinates on the 1-dimensional ring of radius R, the wave function depends only on the angular coordinate, and so [1]
The Hamiltonian of the particle is: ^ = ^ + ^ = ^ + ^, where m is the particle's mass, k is the force constant, = / is the angular frequency of the oscillator, ^ is the position operator (given by x in the coordinate basis), and ^ is the momentum operator (given by ^ = / in the coordinate basis).
In the framework of the de Broglie–Bohm theory, the quantum potential is a term within the Schrödinger equation which acts to guide the movement of quantum particles. . The quantum potential approach introduced by Bohm [1] [2] provides a physically less fundamental exposition of the idea presented by Louis de Broglie: de Broglie had postulated in 1925 that the relativistic wave function ...
Within this framework the molecular Hamiltonian has been simplified to the so-called clamped nucleus Hamiltonian, also called electronic Hamiltonian, that acts only on functions of the electronic coordinates. Once the Schrödinger equation of the clamped nucleus Hamiltonian has been solved for a sufficient number of constellations of the nuclei ...
Let (x, y, z) be the standard Cartesian coordinates, and (ρ, θ, φ) the spherical coordinates, with θ the angle measured away from the +Z axis (as , see conventions in spherical coordinates). As φ has a range of 360° the same considerations as in polar (2 dimensional) coordinates apply whenever an arctangent of it is taken. θ has a range ...
The equation defining a plane curve expressed in polar coordinates is known as a polar equation. In many cases, such an equation can simply be specified by defining r as a function of φ. The resulting curve then consists of points of the form (r(φ), φ) and can be regarded as the graph of the polar function r.