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The pH electrode is an example of a glass electrode that is sensitive to hydrogen ions. Glass electrodes play an important part in the instrumentation for chemical analysis, and physicochemical studies. The voltage of the glass electrode, relative to some reference value, is sensitive to changes in the activity of a certain type of ions.
The design of the electrodes is the key part: These are rod-like structures usually made of glass, with a bulb containing the sensor at the bottom. The glass electrode for measuring the pH has a glass bulb specifically designed to be selective to hydrogen-ion concentration.
Commercial reference electrodes consist of a glass or plastic tube electrode body. The electrode consists of a metallic silver wire (Ag (s)) coated with a thin layer of silver chloride (AgCl), either physically by dipping the wire in molten silver chloride, chemically by electroplating the wire in concentrated hydrochloric acid (HCl) [3] or electrochemically by oxidising the silver at an anode ...
In aquatic environments, platinum is often used due to its high electron transfer kinetics, [5] although an electrode made from several metals can be used in order to enhance the electron transfer kinetics. [6] The most common potentiometric electrode is by far the glass-membrane electrode used in a pH meter.
Primary pH standard values are determined using a concentration cell with transference by measuring the potential difference between a hydrogen electrode and a standard electrode such as the silver chloride electrode. The pH of aqueous solutions can be measured with a glass electrode and a pH meter or a color-changing indicator.
[3]: 134–135 The original pH meter weighed in at nearly 7 kg, but was a substantial improvement over a benchful of delicate equipment. The earliest meter had a design glitch, in that the pH readings changed with the depth of immersion of the electrodes, but Beckman fixed the problem by sealing the glass bulb of the electrode.
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