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In chemistry, an acid–base reaction is a chemical reaction that occurs between an acid and a base.It can be used to determine pH via titration.Several theoretical frameworks provide alternative conceptions of the reaction mechanisms and their application in solving related problems; these are called the acid–base theories, for example, Brønsted–Lowry acid–base theory.
Arrhenius declined, however, as he preferred to stay in Sweden-Norway for a while (his father was very ill and would die in 1885) and had received an appointment at Uppsala. [12] [13] [14] In an extension of his ionic theory Arrhenius proposed definitions for acids and bases, in 1884.
In 1884, Svante Arrhenius proposed that a base is a substance which dissociates in aqueous solution to form hydroxide ions OH −. These ions can react with hydrogen ions (H + according to Arrhenius) from the dissociation of acids to form water in an acid–base reaction. A base was therefore a metal hydroxide such as NaOH or Ca(OH) 2.
[2] [3] The basic concept of this theory is that when an acid and a base react with each other, the acid forms its conjugate base, and the base forms its conjugate acid by exchange of a proton (the hydrogen cation, or H +). This theory generalises the Arrhenius theory.
Niklas Arrhenius (born 1982), Swedish discus thrower; Svante Arrhenius (1859–1927), Swedish physical chemist and 1903 Nobel laureate; Arrhenius definition, Svante Arrhenius definition of acids and bases; Arrhenius equation, Svante Arrhenius formula for modeling the temperature dependence of reaction rate constants; Arrhenius plot
One use of conjugate acids and bases lies in buffering systems, which include a buffer solution. In a buffer, a weak acid and its conjugate base (in the form of a salt), or a weak base and its conjugate acid, are used in order to limit the pH change during a titration process. Buffers have both organic and non-organic chemical applications.
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In physical chemistry, the Arrhenius equation is a formula for the temperature dependence of reaction rates.The equation was proposed by Svante Arrhenius in 1889, based on the work of Dutch chemist Jacobus Henricus van 't Hoff who had noted in 1884 that the van 't Hoff equation for the temperature dependence of equilibrium constants suggests such a formula for the rates of both forward and ...