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There are two major families of fullerenes, with fairly distinct properties and applications: the closed buckyballs and the open-ended cylindrical carbon nanotubes. [27] However, hybrid structures exist between those two classes, such as carbon nanobuds — nanotubes capped by hemispherical meshes or larger "buckybuds".
Fullerene chemistry is a field of organic chemistry devoted to the chemical properties of fullerenes. [1] [2] [3] Research in this field is driven by the need to functionalize fullerenes and tune their properties. For example, fullerene is notoriously insoluble and adding a suitable group can enhance solubility. [1]
The mechanical properties of carbon nanotubes reveal them as one of the strongest materials in nature. Carbon nanotubes (CNTs) are long hollow cylinders of graphene . Although graphene sheets have 2D symmetry, carbon nanotubes by geometry have different properties in axial and radial directions.
Carbon nanotubes, also called buckytubes, are cylindrical carbon molecules with novel properties that make them potentially useful in a wide variety of applications (e.g., nano-electronics, optics, materials applications, etc.). They exhibit extraordinary strength, unique electrical properties, and are efficient conductors of heat.
A transition metal fullerene complex is a coordination complex wherein fullerene serves as a ligand. Fullerenes are typically spheroidal carbon compounds, the most prevalent being buckminsterfullerene, C 60. [2] One year after it was prepared in milligram quantities in 1990, [3] C 60 was shown to function as a ligand in the complex [Ph 3 P] 2 ...
In 2003, room-temperature ballistic transistors with ohmic metal contacts and high-k gate dielectric were reported, showing 20–30x more current than state-of-the-art siliconMOSFETs. Palladium is a high-work function metal that was shown to exhibit Schottky barrier-free contacts to semiconducting nanotubes with diameters >1.7 nm. [93]
Carbon nanofibers (CNFs), vapor grown carbon fibers (VGCFs), or vapor grown carbon nanofibers (VGCNFs) are cylindrical nanostructures with graphene layers arranged as stacked cones, cups or plates. Carbon nanofibers with graphene layers wrapped into perfect cylinders are called carbon nanotubes.
The fullerenes are a class of allotropes of carbon which conceptually are graphene sheets rolled into tubes or spheres. These include the carbon nanotubes (or silicon nanotubes ) which are of interest both because of their mechanical strength and also because of their electrical properties.