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Atmospheric pollutant concentrations expressed as mass per unit volume of atmospheric air (e.g., mg/m 3, μg/m 3, etc.) at sea level will decrease with increasing altitude because the atmospheric pressure decreases with increasing altitude. The change of atmospheric pressure with altitude can be obtained from this equation: [2]
As an example, a measured NO x concentration of 45 ppmv in a dry gas having 5 volume % O 2 is: 45 × ( 20.9 - 3 ) ÷ ( 20.9 - 5 ) = 50.7 ppmv of NO x. when corrected to a dry gas having a specified reference O 2 content of 3 volume %. Note: The measured gas concentration C m must first be corrected to a dry basis before using the above equation.
As a more complex example, the concentration of nitrogen oxides (NO x) in the flue gas from an industrial furnace can be converted to a mass flow rate expressed in grams per hour (g/h) of NO x by using the following information as shown below: NO x concentration = 10 parts per million by volume = 10 ppmv = 10 volumes/10 6 volumes NO x molar mass
To calculate the density of air as a function of altitude, one requires additional parameters. For the troposphere, the lowest part (~10 km) of the atmosphere, they are listed below, along with their values according to the International Standard Atmosphere , using for calculation the universal gas constant instead of the air specific constant:
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