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In organic chemistry, the E i mechanism (Elimination Internal/Intramolecular), also known as a thermal syn elimination or a pericyclic syn elimination, is a special type of elimination reaction in which two vicinal (adjacent) substituents on an alkane framework leave simultaneously via a cyclic transition state to form an alkene in a syn elimination. [1]
Electron ionization (EI, formerly known as electron impact ionization [1] and electron bombardment ionization [2]) is an ionization method in which energetic electrons interact with solid or gas phase atoms or molecules to produce ions. [3] EI was one of the first ionization techniques developed for mass spectrometry. [4]
For example, hexane fragmentation patterns. The m/z=57 butyl cation is the base peak, and other most abundant peaks in the spectrum are alkyl carbocations at m/z=15, 29, 43 Da. [6] [2] [11] The possible mechanisms for EI ionization spectra of hexane. Branched alkanes have somewhat weaker molecular ion peaks in the spectra.
An elimination reaction is a type of organic reaction in which two substituents are removed from a molecule in either a one- or two-step mechanism. [2] The one-step mechanism is known as the E2 reaction, and the two-step mechanism is known as the E1 reaction. The numbers refer not to the number of steps in the mechanism, but rather to the ...
For real non-zero values of x, the exponential integral Ei(x) is defined as = =. The Risch algorithm shows that Ei is not an elementary function.The definition above can be used for positive values of x, but the integral has to be understood in terms of the Cauchy principal value due to the singularity of the integrand at zero.
Emotional intelligence (EI), also known as emotional quotient (EQ), is the ability to perceive, use, understand, manage, and handle emotions.High emotional intelligence includes emotional recognition of emotions of the self and others, using emotional information to guide thinking and behavior, discerning between and labeling of different feelings, and adjusting emotions to adapt to environments.
Immediate early genes (IEGs) are genes which are activated transiently and rapidly in response to a wide variety of cellular stimuli. They represent a standing response mechanism that is activated at the transcription level in the first round of response to stimuli, before any new proteins are synthesized.
A Jablonski diagram describing the mechanism of triplet-triplet annihilation. The energy of the first triplet excited state (T 1) is transferred to a second triplet excited state (T 1), resulting in (1) the first T 1 returning to the singlet ground state S0 and (2) the second T 1 promoting to the singlet excited state (S 1).