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Mass transfer is the net movement of mass from one location (usually meaning stream, phase, fraction, or component) to another. Mass transfer occurs in many processes, such as absorption, evaporation, drying, precipitation, membrane filtration, and distillation. Mass transfer is used by different scientific disciplines for different processes ...
Mass transfer in a system is governed by Fick's first law: 'Diffusion flux from higher concentration to lower concentration is proportional to the gradient of the concentration of the substance and the diffusivity of the substance in the medium.' Mass transfer can take place due to different driving forces. Some of them are: [12]
For example, in chemical reactions, the mass of the chemical components before the reaction is equal to the mass of the components after the reaction. Thus, during any chemical reaction and low-energy thermodynamic processes in an isolated system, the total mass of the reactants, or starting materials, must be equal to the mass of the products.
The self-diffusion coefficient of neat water is: 2.299·10 −9 m 2 ·s −1 at 25 °C and 1.261·10 −9 m 2 ·s −1 at 4 °C. [2] Chemical diffusion occurs in a presence of concentration (or chemical potential) gradient and it results in net transport of mass. This is the process described by the diffusion equation.
It is derived using the scalar field's conservation law, together with Gauss's theorem, and taking the infinitesimal limit. One easily visualized example of advection is the transport of ink dumped into a river. As the river flows, ink will move downstream in a "pulse" via advection, as the water's movement itself transports the ink.
The general form quoted for a mass balance is The mass that enters a system must, by conservation of mass, either leave the system or accumulate within the system. Mathematically the mass balance for a system without a chemical reaction is as follows: [2]: 59–62
Fick's first law relates the diffusive flux to the gradient of the concentration. It postulates that the flux goes from regions of high concentration to regions of low concentration, with a magnitude that is proportional to the concentration gradient (spatial derivative), or in simplistic terms the concept that a solute will move from a region of high concentration to a region of low ...
The movement of a fluid through porous media is described by the combination of Darcy's law with the principle of conservation of mass in order to express the capillary force or fluid velocity as a function of various other parameters including the effective pore radius, liquid viscosity or permeability. [3]