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The table above gives properties of the vapor–liquid equilibrium of anhydrous ammonia at various temperatures. The second column is vapor pressure in kPa. The third column is the density of the liquid phase. The fourth column is the density of the vapor.
Household 'ammonia' is a solution of NH 3 in water, and is used as a general purpose cleaner for many surfaces. Because ammonia results in a relatively streak-free shine, one of its most common uses is to clean glass, porcelain, and stainless steel. It is also frequently used for cleaning ovens and for soaking items to loosen baked-on grime.
Nitrification inhibitors are used widely, being added to approximately 50% of the fall-applied anhydrous ammonia in states in the U.S., like Illinois. [42] They are usually effective in increasing recovery of nitrogen fertilizer in row crops, but the level of effectiveness depends on external conditions and their benefits are most likely to be ...
Anhydrous solvents are commercially available from chemical suppliers, and are packaged in sealed containers to maintain dryness. [4] Typically anhydrous solvents will contain approximately 10 ppm of water and will increase in wetness if they are not properly stored. Organic solutions can be dried using a range of drying agents.
Liquid ammonia has a very high standard enthalpy change of vapourization (23.5 kJ/mol; [28] for comparison, water's is 40.65 kJ/mol, methane 8.19 kJ/mol and phosphine 14.6 kJ/mol) and can be transported in pressurized or refrigerated vessels; however, at standard temperature and pressure liquid anhydrous ammonia will vaporize.
As of 2018, the Haber process produces 230 million tonnes of anhydrous ammonia per year. [69] The ammonia is used mainly as a nitrogen fertilizer as ammonia itself, in the form of ammonium nitrate, and as urea. The Haber process consumes 3–5% of the world's natural gas production (around 1–2% of the world's energy supply).
Ammonia electrolysis may require much less thermodynamic energy than water electrolysis (only 0.06 V in alkaline media). [23] Another option for recovering ammonia from wastewater is to use the mechanics of the ammonia-water thermal absorption cycle. [24] [25] Ammonia can thus be recovered either as a liquid or as ammonium hydroxide. The ...
4. The water-absorbing nature of anhydrous ammonia that causes the greatest injury (especially to the eyes, nose, throat or lungs), and which can cause permanent damage. It is a colourless gas at atmospheric pressure and normal temperature, but under pressure readily changes into a liquid. Anhydrous ammonia has a high affinity for water.