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Calcium-silicate passive fire protection board being clad around steel structure in order to achieve a fire-resistance rating. Calcium silicate is commonly used as a safe alternative to asbestos for high-temperature insulation materials. Industrial-grade piping and equipment insulation is often fabricated from calcium silicate.
Only calcium silicates contribute to the strength. Tricalcium silicate is responsible for most of the early strength (first 7 days). [3] Dicalcium silicate, which reacts more slowly, only contributes to late strength. Calcium silicate hydrate (also shown as C-S-H) is a result of the reaction between the silicate phases of Portland cement and water.
Larnite is a calcium silicate mineral with the formula Ca 2 SiO 4.It is the calcium member of the olivine group of minerals.. It was first described from an occurrence at Scawt Hill, Larne, Northern Ireland in 1929 by Cecil Edgar Tilley and named for the location. [2]
The other silicate, alite contributes "early" strength, due to its higher reactivity. Belite reacts with water (roughly) to form calcium silicate hydrates (C-S-H) and portlandite (Ca(OH) 2) according to the reaction:
These substances break down into dissolved ions as a result. For example, calcium silicate (CaSiO 3), or wollastonite, reacts with carbon dioxide and water to yield a calcium ion, Ca 2+, a bicarbonate ion, HCO 3 −, and dissolved silica. This reaction structure is representative of general silicate weathering of calcium silicate minerals. [9]
Thaumasite is a calcium silicate mineral, containing Si atoms in unusual octahedral configuration, with chemical formula Ca 3 Si(OH) 6 (C O 3)(SO 4)·12H 2 O, also sometimes more simply written as CaSiO 3 ·CaCO 3 ·CaSO 4 ·15H 2 O. It occurs as colorless to white prismatic hexagonal crystals, typically as acicular radiating groups. It also ...
Wollastonite is a calcium inosilicate mineral (Ca Si O 3) that may contain small amounts of iron, magnesium, and manganese substituting for calcium. It is usually white. It forms when impure limestone or dolomite is subjected to high temperature and pressure, which sometimes occurs in the presence of silica-bearing fluids as in skarns [7] or in contact with metamorphic rocks.
Calcium ions then react with the soluble sodium silicate gel to convert it into solid calcium silicate hydrates (C-S-H). The C-S-H forms a continuous poorly permeable coating at the external surface of the aggregate. The penetrated alkaline solution (NaOH / KOH) converts the remaining siliceous minerals into bulky soluble alkali silicate gel.
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