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tert-Butyl bromide (also referred to as 2-bromo-2-methylpropane) is an organic compound with the formula Me 3 CBr (Me = methyl). The molecule features a tert-butyl group attached to a bromide substituent. This organobromine compound is used as a standard reagent in synthetic organic chemistry. It is a colorless liquid.
Whereas the relatively unreactive bromine reacts with 2-methylbutane predominantly to 2-bromo-2-methylbutane, the reaction with much more reactive chlorine results in a mixture of all four regioisomers. Another example of RSP can be found in the selectivity of the reaction of certain carbocations with azides and water.
2-Bromobutane is an isomer of 1-bromobutane. Both compounds share the molecular formula C 4 H 9 Br. 2-Bromobutane is also known as sec-butyl bromide or methylethylbromomethane. Because it contains bromine, a halogen, it is part of a larger class of compounds known as alkyl halides. It is a colorless liquid with a pleasant odor.
For example, treating 2-Bromo-2-methyl butane with sodium ethoxide in ethanol produces the Zaytsev product with moderate selectivity. [9] Due to steric interactions, a bulky base – such as potassium tert-butoxide, triethylamine, or 2,6-lutidine – cannot readily abstract the proton that would lead to the Zaytsev product. In these situations ...
2-Bromopentane [1] (chiral) 3-Bromopentane; There are four isomers of monobromopentane based on 2-methylbutane: 1-Bromo-2-methylbutane (chiral) 1-Bromo-3-methylbutane; 2-Bromo-2-methylbutane; 2-Bromo-3-methylbutane (chiral) 2,2-Dimethylpropane has only one monobrominated derivative, 1-bromo-2,2-dimethylpropane, also known as neopentyl bromide. [2]
2-Bromopropane, also known as isopropyl bromide and 2-propyl bromide, is the halogenated hydrocarbon with the formula CH 3 CHBrCH 3. It is a colorless liquid. It is a colorless liquid. It is used for introducing the isopropyl functional group in organic synthesis . 2-Bromopropane is prepared by heating isopropanol with hydrobromic acid .
1-Bromobutane is the organobromine compound with the formula CH 3 (CH 2) 3 Br. It is a colorless liquid, although impure samples appear yellowish. It is insoluble in water, but soluble in organic solvents. It is primarily used as a source of the butyl group in organic synthesis. It is one of several isomers of butyl bromide.
[4] [5] In following the mechanism is described using trimethylamine as example: [6] First, the trimethylamine reacts with the cyanogen bromide to form a quaternary ammonium salt, which in the next step reacts by splitting off bromomethane to give the dimethylcyanamide. This is a second-order nucleophilic substitution (S N 2).