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The Larmor frequency is important in NMR spectroscopy. The gyromagnetic ratios, which give the Larmor frequencies at a given magnetic field strength, have been measured and tabulated. [3] Crucially, the Larmor frequency is independent of the polar angle between the applied magnetic field and the magnetic moment direction.
Taking for example the H 2 O molecules in liquid phase without the contamination of oxygen-17, the value of K is 1.02×10 10 s −2 and the correlation time is on the order of picoseconds = s, while hydrogen nuclei 1 H at 1.5 tesla precess at a Larmor frequency of approximately 64 MHz (Simplified. BPP theory uses angular frequency indeed).
Solving gives the angular frequency (Larmor frequency) with the magnetic field pointing on z-axis: = The minus sign is necessary. It reflects that the J is rotating in left-hand when the thumb is pointing as the H field. when turned on the rotating magnetic field (B R), with angular frequency ω. In the rotating frame of the rotating field, the ...
As with any magnet, this torque is proportional the product of the magnetic moment and the external magnetic field strength. Since the nucleons have spin angular momentum, this torque will cause them to precess with a well-defined frequency, called the Larmor frequency. It is this phenomenon that enables the measurement of nuclear properties ...
A simplified version of the Rabi method consists of a beam of atoms, all having the same speed and the same direction, sent through one interaction zone of length .The atoms are two-level atoms with a transition energy of (this is defined by applying a field ‖ in an excitation direction ^, and thus = | ‖ |, the Larmor frequency), and with an interaction time of = / in the interaction zone.
The relationship between the frequency of the induced current and the strength of the magnetic field is called the proton gyromagnetic ratio, and is equal to 0.042576 Hz nT −1. Because the precession frequency depends only on atomic constants and the strength of the ambient magnetic field, the accuracy of this type of magnetometer can reach 1 ...
The Rabi frequency is a semiclassical concept since it treats the atom as an object with quantized energy levels and the electromagnetic field as a continuous wave. In the context of a nuclear magnetic resonance experiment, the Rabi frequency is the nutation frequency of a sample's net nuclear magnetization vector about a radio-frequency field.
A molecular vibration is a periodic motion of the atoms of a molecule relative to each other, such that the center of mass of the molecule remains unchanged. The typical vibrational frequencies range from less than 10 13 Hz to approximately 10 14 Hz, corresponding to wavenumbers of approximately 300 to 3000 cm −1 and wavelengths of approximately 30 to 3 μm.