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  2. 3-Methylhexane - Wikipedia

    en.wikipedia.org/wiki/3-Methylhexane

    3-Methylhexane is a branched hydrocarbon with two enantiomers. [2] It is one of the isomers of heptane. The molecule is chiral, and is one of the two isomers of heptane to have this property, the other being its structural isomer 2,3-dimethylpentane. The enantiomers are (R)-3-methylhexane [3] and (S)-3-methylhexane. [4]

  3. Transhalogenation - Wikipedia

    en.wikipedia.org/wiki/Transhalogenation

    C 3 H 5-Cl + NaF → R-F + NaCl This kind of reaction is called Finkelstein reaction . [ 2 ] However, it is also possible, for example, to produce phosphorus fluoride compounds by transhalogenating chlorine, bromine or iodine bound to phosphorus with a metal fluoride.

  4. Haloform reaction - Wikipedia

    en.wikipedia.org/wiki/Haloform_reaction

    In chemistry, the haloform reaction (also referred to as the Lieben haloform reaction) is a chemical reaction in which a haloform (CHX 3, where X is a halogen) is produced by the exhaustive halogenation of an acetyl group (R−C(=O)CH 3, where R can be either a hydrogen atom, an alkyl or an aryl group), in the presence of a base.

  5. Hydrohalogenation - Wikipedia

    en.wikipedia.org/wiki/Hydrohalogenation

    By reaction with tertiary amines, long-chain alkyl bromides such as 1-bromododecane, give quaternary ammonium salts, which are used as phase transfer catalysts. [ 9 ] With Michael acceptors the addition is also anti-Markovnikov because now a nucleophilic X − reacts in a nucleophilic conjugate addition for example in the reaction of HCl with ...

  6. Dewar–Chatt–Duncanson model - Wikipedia

    en.wikipedia.org/wiki/Dewar–Chatt–Duncanson...

    On the right, an empty pi-antibonding orbital on C 2 H 4 overlaps with a filled d-orbital on the metal. The Dewar–Chatt–Duncanson model is a model in organometallic chemistry that explains the chemical bonding in transition metal alkene complexes. The model is named after Michael J. S. Dewar, [1] Joseph Chatt and L. A. Duncanson. [2] [3]

  7. Hofmann–Löffler reaction - Wikipedia

    en.wikipedia.org/wiki/Hofmann–Löffler_reaction

    The Suárez modification of the Hofmann–Löffler–Freytag reaction was the basis of the new synthetic method developed by H. Togo et al. [42] [43] The authors demonstrated that various N-alkylsaccharins (N-alkyl-1,2-benzisothiazoline-3-one-1,1,-dioxides) 77 are easily prepared in moderate to good yields by the reaction of N-alkyl(o-methyl ...

  8. Carius halogen method - Wikipedia

    en.wikipedia.org/wiki/Carius_halogen_method

    The Carius halogen method in analytical chemistry is a method for the quantitative determination of halogens in chemical substances. [1]A known mass of an organic compound is heated with fuming nitric acid in the presence of silver nitrate contained in a hard glass tube known as carius tube, in a furnace.

  9. 2,2,4-Trimethylpentane - Wikipedia

    en.wikipedia.org/wiki/2,2,4-Trimethylpentane

    2,2,4-Trimethylpentane, also known as isooctane or iso-octane, is an organic compound with the formula (CH 3) 3 CCH 2 CH(CH 3) 2. It is one of several isomers of octane (C 8 H 18 ). This particular isomer is the standard 100 point on the octane rating scale (the zero point is n -heptane ).