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Sulfuryl chloride is used as a source of Cl 2.Because it is a pourable liquid, it is considered more convenient than Cl 2 to dispense.. Sulfuryl chloride is used in the conversion of C−H to C−Cl adjacent to activating substituents such as carbonyls and sulfoxides: [5] [6]
This improper name persists, especially in elementary textbooks. In biology, the unit "%" is sometimes (incorrectly) used to denote mass concentration, also called mass/volume percentage. A solution with 1 g of solute dissolved in a final volume of 100 mL of solution would be labeled as "1%" or "1% m/v" (mass/volume). This is incorrect because ...
In chemistry, the mass concentration ρ i (or γ i) is defined as the mass of a constituent m i divided by the volume of the mixture V. [1]= For a pure chemical the mass concentration equals its density (mass divided by volume); thus the mass concentration of a component in a mixture can be called the density of a component in a mixture.
Conversion and its related terms yield and selectivity are important terms in chemical reaction engineering.They are described as ratios of how much of a reactant has reacted (X — conversion, normally between zero and one), how much of a desired product was formed (Y — yield, normally also between zero and one) and how much desired product was formed in ratio to the undesired product(s) (S ...
CSI is prepared by treating cyanogen chloride with sulfur trioxide, the product being distilled directly from the reaction mixture. [1] SO 3 + ClCN → ClSO 2 NCO. In this transformation, both the carbon and the nitrogen termini of CN are functionalized. The structure of CSI is represented as ClS(O) 2-N=C=O.
In chemistry, a sulfonyl halide consists of a sulfonyl (>S(=O) 2) group singly bonded to a halogen atom. They have the general formula RSO 2 X, where X is a halogen.The stability of sulfonyl halides decreases in the order fluorides > chlorides > bromides > iodides, all four types being well known.
It adds to alkenes to give chloride-substituted thioethers. Illustrative is its addition to 1,5-cyclooctadiene to give a bicyclic thioether [2] A well tested method for the production of the mustard gas bis(2-chloroethyl)sulfide, is the addition of ethylene to sulfur dichloride: [3] SCl 2 + 2 C 2 H 4 → (ClC 2 H 4) 2 S
In inorganic chemistry, the sulfuryl group is a functional group consisting of a sulfur atom covalently bound to two oxygen atoms (S(=O) 2 X 2). It occurs in compounds such as sulfuryl chloride , SO 2 Cl 2 and sulfuryl fluoride , SO 2 F 2 .