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A specific property is the intensive property obtained by dividing an extensive property of a system by its mass. For example, heat capacity is an extensive property of a system. Dividing heat capacity, , by the mass of the system gives the specific heat capacity, , which is an intensive property. When the extensive property is represented by ...
The state of a simple compressible system is completely specified by two independent, intensive properties [2] A more general statement of the state postulate says: the state of a simple system is completely specified by r+1 independent, intensive properties where r is the number of significant work interactions. [1] [3]
Only in a quasi-static thermodynamic process can we exactly define intensive quantities (such as pressure, temperature, specific volume, specific entropy) of the system at any instant during the whole process; otherwise, since no internal equilibrium is established, different parts of the system would have different values of these quantities ...
The pressure is the intensive generalized force, while the volume change is the extensive generalized displacement: δ W = P d V . {\displaystyle \delta W=P\,\mathrm {d} V.} This defines the direction of work, W {\displaystyle W} , to be energy transfer from the working system to the surroundings, indicated by a positive term.
The second law refers to a system of matter and radiation, initially with inhomogeneities in temperature, pressure, chemical potential, and other intensive properties, that are due to internal 'constraints', or impermeable rigid walls, within it, or to externally imposed forces.
Extensive parameters are properties of the entire system, as contrasted with intensive parameters which can be defined at a single point, such as temperature and pressure. The extensive parameters (except entropy) are generally conserved in some way as long as the system is "insulated" to changes to that parameter from the outside. The truth of ...
The final column lists some special properties that some of the quantities have, such as their scaling behavior (i.e. whether the quantity is intensive or extensive), their transformation properties (i.e. whether the quantity is a scalar, vector, matrix or tensor), and whether the quantity is conserved.
In the thermodynamics of equilibrium, a state function, function of state, or point function for a thermodynamic system is a mathematical function relating several state variables or state quantities (that describe equilibrium states of a system) that depend only on the current equilibrium thermodynamic state of the system [1] (e.g. gas, liquid, solid, crystal, or emulsion), not the path which ...