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  2. Tetrairidium dodecacarbonyl - Wikipedia

    en.wikipedia.org/wiki/Tetrairidium_dodecacarbonyl

    Each Ir center is octahedral, being bonded to 3 other iridium atoms and three terminal CO ligands. Ir 4 (CO) 12 has T d symmetry with an average Ir-Ir distances of 2.693 Å. [4] The related clusters Rh 4 (CO) 12 and Co 4 (CO) 12 have C 3v symmetry because of the presence of three bridging CO ligands in each.

  3. Niterra - Wikipedia

    en.wikipedia.org/wiki/Niterra

    Niterra established its first European subsidiary, NGK SPARK PLUG (U.K.) Ltd. in 1975. In 1979, its second European subsidiary, NGK SPARK PLUG DEUTSCHLAND GmbH, was founded in Germany. [6] Ten years later, it was renamed NGK SPARK PLUG EUROPE GmbH when it took charge of operations in Europe. In 2017, its remit further expanded across the EMEA ...

  4. Group 9 element - Wikipedia

    en.wikipedia.org/wiki/Group_9_element

    Of the group 9 elements, only cobalt has a biological role. It is a key constituent of cobalamin, also known as vitamin B 12, the primary biological reservoir of cobalt as an ultratrace element. [21] [22] Bacteria in the stomachs of ruminant animals convert cobalt salts into vitamin B 12, a compound which can only be produced by bacteria or ...

  5. Organoiridium chemistry - Wikipedia

    en.wikipedia.org/wiki/Organoiridium_chemistry

    Organoiridium compounds share many characteristics with those of rhodium, but less so with cobalt. Iridium can exist in oxidation states of -III to +V, but iridium(I) and iridium(III) are the more common. iridium(I) compounds (d 8 configuration) usually occur with square planar or trigonal bipyramidal geometries, whereas iridium(III) compounds (d 6 configuration) typically have an octahedral ...

  6. Iridium - Wikipedia

    en.wikipedia.org/wiki/Iridium

    Iridium compounds are used as catalysts in the Cativa process for carbonylation of methanol to produce acetic acid. [92] [93] Iridium complexes are often active for asymmetric hydrogenation both by traditional hydrogenation. [94] and transfer hydrogenation. [95] This property is the basis of the industrial route to the chiral herbicide (S ...

  7. Transition metal - Wikipedia

    en.wikipedia.org/wiki/Transition_metal

    In the second row, the maximum occurs with ruthenium (+8), and in the third row, the maximum occurs with iridium (+9). In compounds such as [MnO 4] − and OsO 4, the elements achieve a stable configuration by covalent bonding. The lowest oxidation states are exhibited in metal carbonyl complexes such as Cr(CO) 6 (oxidation state zero) and [Fe(CO)

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