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A solution in radicals or algebraic solution is an expression of a solution of a polynomial equation that is algebraic, that is, relies only on addition, subtraction, multiplication, division, raising to integer powers, and extraction of n th roots (square roots, cube roots, etc.). A well-known example is the quadratic formula
The final step is called termination (6,7), in which the radical recombines with another radical species. If the reaction is not terminated, but instead the radical group(s) go on to react further, the steps where new radicals are formed and then react are collectively known as propagation (4,5). This is because a new radical is created, able ...
The formed product, a carbon radical, can react with non-radical molecule to continue propagation or react with another radical to form a new stable molecule such as a longer carbon chain or an alkyl halide. [4] The example below of methane chlorination shows a multi-step reaction involving radicals.
In general, whenever we multiply both sides of an equation by an expression involving variables, we introduce extraneous solutions wherever that expression is equal to zero. But it is not sufficient to exclude these values, because they may have been legitimate solutions to the original equation.
Photodissociation of source molecules produces other radicals. In the lower atmosphere, important radical are produced by the photodissociation of nitrogen dioxide to an oxygen atom and nitric oxide (see eq. 1.1 below), which plays a key role in smog formation—and the photodissociation of ozone to give the excited oxygen atom O(1D) (see eq. 1 ...
Radical disproportionation encompasses a group of reactions in organic chemistry in which two radicals react to form two different non-radical products. Radicals in chemistry are defined as reactive atoms or molecules that contain an unpaired electron or electrons in an open shell. The unpaired electrons can cause radicals to be unstable and ...
Chain propagation: A radical reacts with a non-radical to produce a new radical species; Chain termination: Two radicals react with each other to create a non-radical species; In a free-radical addition, there are two chain propagation steps. In one, the adding radical attaches to a multiply-bonded precursor to give a radical with lesser bond ...
is the simplest equation that cannot be solved in radicals, and that almost all polynomials of degree five or higher cannot be solved in radicals. The impossibility of solving in degree five or higher contrasts with the case of lower degree: one has the quadratic formula, the cubic formula, and the quartic formula for degrees two, three, and ...