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A PV diagram plots the change in pressure P with respect to volume V for some process or processes. Typically in thermodynamics, the set of processes forms a cycle, so that upon completion of the cycle there has been no net change in state of the system; i.e. the device returns to the starting pressure and volume.
The pressure on a pressure-temperature diagram (such as the water phase diagram shown above) is the partial pressure of the substance in question. A phase diagram in physical chemistry , engineering , mineralogy , and materials science is a type of chart used to show conditions (pressure, temperature, etc.) at which thermodynamically distinct ...
All three diagrams are derived from the physical P–alpha diagram which combines pressure (P) and specific volume (alpha) as its basic coordinates. The P–alpha diagram shows a strong deformation of the grid for atmospheric conditions and is therefore not useful in atmospheric sciences. The three diagrams are constructed from the P–alpha ...
Pressure, temperature, enthalpy, entropy, specific volume, and internal energy are the most common. Pressure–volume diagram showing state (p,V) If at least two thermodynamic properties are known, the state of the working fluid can be defined. This is usually done on a property diagram which is simply a plot of one property versus another.
Because the net variation in state properties during a thermodynamic cycle is zero, it forms a closed loop on a P-V diagram. A P-V diagram's abscissa, Y axis, shows pressure (P) and ordinate, X axis, shows volume (V). The area enclosed by the loop is the net work done by the processes, i.e. the cycle:
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The phase space can also refer to the space that is parameterized by the macroscopic states of the system, such as pressure, temperature, etc. For instance, one may view the pressure–volume diagram or temperature–entropy diagram as describing part of this phase space. A point in this phase space is correspondingly called a macrostate.