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1,1,2,2-Tetrabromoethane, or simply tetrabromoethane (TBE), is a halogenated hydrocarbon, chemical formula C 2 H 2 Br 4.Although three bromine atoms may bind to one of the carbon atoms creating 1,1,1,2-tetrabromoethane this is not thermodynamically favorable, so in practice tetrabromoethane is equal to 1,1,2,2-tetrabromoethane, where each carbon atom binds two bromine atoms.
Tribromoethylene is a bromoalkene and a trihaloethylene with the chemical formula C 2 HBr 3.It can be made from 1,1,2,2-tetrabromoethane. [3]Tribromoethylene reacts with potassium hydroxide to yield dibromoacetylene via dehydrobromination, [4] this reaction is analogous to the synthesis of dichloroacetylene from trichloroethylene.
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Monoclinic polymorph has space group C2/c with lattice constants: a = 20.9, b = 12.1, c = 21.2 (.10 −1 nm), β = 110.5°. [5] Bond energy of C–Br is 235 kJ.mol −1. [6] Due to its symmetrically substituted tetrahedral structure, its dipole moment is 0 Debye. Critical temperature is 439 °C (712 K) and critical pressure is 4.26 MPa. [5]
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