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In thermodynamics, the compressibility factor (Z), also known as the compression factor or the gas deviation factor, describes the deviation of a real gas from ideal gas behaviour. It is simply defined as the ratio of the molar volume of a gas to the molar volume of an ideal gas at the same temperature and pressure .
For ordinary materials, the bulk compressibility (sum of the linear compressibilities on the three axes) is positive, that is, an increase in pressure squeezes the material to a smaller volume. This condition is required for mechanical stability. [8] However, under very specific conditions, materials can exhibit a compressibility that can be ...
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These dimensionless thermodynamic coordinates, taken together with a substance's compressibility factor, provide the basis for the simplest form of the theorem of corresponding states. [1] Reduced properties are also used to define the Peng–Robinson equation of state, a model designed to provide reasonable accuracy near the critical point. [2]
The virial expansion is a model of thermodynamic equations of state.It expresses the pressure P of a gas in local equilibrium as a power series of the density.This equation may be represented in terms of the compressibility factor, Z, as = + + + This equation was first proposed by Kamerlingh Onnes. [1]
Thermodynamic data is usually presented as a table or chart of function values for one mole of a substance (or in the case of the steam tables, one kg). A thermodynamic datafile is a set of equation parameters from which the numerical data values can be calculated. Tables and datafiles are usually presented at a standard pressure of 1 bar or 1 ...
Consequently, there is a pressing need to study their thermal properties. [ 68 ] In the same section, Boltzmann also addressed and explained the negative pressures which some liquid metastable states exhibit (for example, the blue isotherm T r = 4 / 5 {\displaystyle T_{\text{r}}=4/5} in Fig. 1).
1 Including a compressibility chart. 1 comment. Toggle the table of contents. Talk: Compressibility chart. Add languages. ... Download as PDF; Printable version ...