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This website is also cited in the CRC Handbook as source of Section 1, subsection Electron Configuration of Neutral Atoms in the Ground State. 91 Pa : [Rn] 5f 2 (3 H 4) 6d 7s 2; 92 U : [Rn] 5f 3 (4 I o 9/2) 6d 7s 2; 93 Np : [Rn] 5f 4 (5 I 4) 6d 7s 2; 103 Lr : [Rn] 5f 14 7s 2 7p 1 question-marked; 104 Rf : [Rn] 5f 14 6d 2 7s 2 question-marked
Any other configuration is an excited state. As an example, the ground state configuration of the sodium atom is 1s 2 2s 2 2p 6 3s 1, as deduced from the Aufbau principle (see below). The first excited state is obtained by promoting a 3s electron to the 3p subshell, to obtain the 1s 2 2s 2 2p 6 3p 1 configuration, abbreviated as the 3p level ...
Grayed out electron numbers indicate subshells filled to their maximum. Bracketed noble gas symbols on the left represent inner configurations that are the same in each period. Written out, these are: He, 2, helium : 1s 2 Ne, 10, neon : 1s 2 2s 2 2p 6 Ar, 18, argon : 1s 2 2s 2 2p 6 3s 2 3p 6 Kr, 36, krypton : 1s 2 2s 2 2p 6 3s 2 3p 6 4s 2 3d 10 ...
LS coupling is for a parent ion and J 1 L 2 coupling is for a coupling of the parent ion and the excited electron. The parent ion is an unexcited part of the atom. For example, in Ar atom excited from a ground state ...3p 6 to an excited state ...3p 5 4p in electronic configuration, 3p 5 is for the parent ion while 4p is for the excited ...
The HF electron configuration 1σ 2 2σ 2 3σ 2 1π 4 reflects that the other electrons remain in three lone pairs and that the bond order is 1. The more electronegative atom is the more energetically excited because it more similar in energy to its atomic orbital.
Atoms can be excited by heat, electricity, or light. The hydrogen atom provides a simple example of this concept.. The ground state of the hydrogen atom has the atom's single electron in the lowest possible orbital (that is, the spherically symmetric "1s" wave function, which, so far, has been demonstrated to have the lowest possible quantum numbers).
Electron affinity can be defined in two equivalent ways. First, as the energy that is released by adding an electron to an isolated gaseous atom. The second (reverse) definition is that electron affinity is the energy required to remove an electron from a singly charged gaseous negative ion.
Core charge can also be calculated as 'atomic number' minus 'all electrons except those in the outer shell'. For example, chlorine (element 17), with electron configuration 1s 2 2s 2 2p 6 3s 2 3p 5, has 17 protons and 10 inner shell electrons (2 in the first shell, and 8 in the second) so: Core charge = 17 − 10 = +7